4.8 Article

Size-dependent propagation of Au nanoclusters through few-layer graphene

Journal

NANOSCALE
Volume 6, Issue 3, Pages 1258-1263

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr04770a

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Funding

  1. Higher Education Funding Council for England (HEFCE)
  2. Engineering and Physical Sciences Research Council [EP/K006061/1] Funding Source: researchfish
  3. EPSRC [EP/K006061/1] Funding Source: UKRI

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We report the size-dependent propagation of gold nanoclusters through few-layer graphene (FLG). We employ aberration-corrected scanning transmission electron microscopy (STEM) to track the fate of Au-55 and Au-923 clusters that have been deposited, independently and isoenergetically, onto suspended FLG films using cluster beam deposition. We demonstrate that Au-55 clusters penetrate through the FLG, whereas the monodisperse Au-923 clusters reside at the surface. Our approach offers a route to the controlled incorporation of dopant nanoparticles and the generation of nanoscale defects in graphene.

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