Stabilized gold clusters: from isolation toward controlled synthesis

Toward an Atomic-Level Understanding of Size-Specific Properties of Protected and Stabilized Gold Clusters

(2012) Tatsuya Tsukuda   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Selective synthesis of organogold magic clusters Au54(CCPh)26

(2012) Prasenjit Maity et al.   CHEMICAL COMMUNICATIONS

Site-Selective Cu Deposition on Pt Dendrimer-Encapsulated Nanoparticles: Correlation of Theory and Experiment

(2012) Emily V. Carino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interlocked Catenane-Like Structure Predicted in Au24(SR)20: Implication to Structural Evolution of Thiolated Gold Clusters from Homoleptic Gold(I) Thiolates to Core-Stacked Nanoparticles

(2012) Yong Pei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atomically precise gold nanocrystal molecules with surface plasmon resonance

(2012) H. Qian et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Mechanism and Active Sites of the Oxidation of CO over Au/TiO2

(2011) Tadahiro Fujitani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and electrospray mass spectrometry determination of thiolate-protected Au55(SR)31 nanoclusters

(2011) Huifeng Qian et al.   CHEMICAL COMMUNICATIONS

Palladium doping of magic gold cluster Au38(SC2H4Ph)24: formation of Pd2Au36(SC2H4Ph)24with higher stability than Au38(SC2H4Ph)24

(2011) Yuichi Negishi et al.   CHEMICAL COMMUNICATIONS

197Au Mössbauer Spectroscopy of Au25(SG)18−Revisited

(2011) Tatsuya Tsukuda et al.   CHEMISTRY LETTERS

Ambient Synthesis of Au144(SR)60Nanoclusters in Methanol

(2011) Huifeng Qian et al.   CHEMISTRY OF MATERIALS

Production of an ordered (B2) CuPd nanoalloy by low-temperature annealing under hydrogen atmosphere

(2011) Miho Yamauchi et al.   DALTON TRANSACTIONS

The Structure and Bonding of Au25(SR)18 Nanoclusters from EXAFS: The Interplay of Metallic and Molecular Behavior

(2011) Mark A. MacDonald et al.   Journal of Physical Chemistry C

Electronic Structure and Bonding of Icosahedral Core–Shell Gold–Silver Nanoalloy Clusters Au144–xAgx(SR)60

(2011) Sami Malola et al.   Journal of Physical Chemistry Letters

Platonic Hexahedron Composed of Six Organic Faces with an Inscribed Au Cluster

(2011) Masanori Sakamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Faradaurate Nanomolecules: A Superstable Plasmonic 76.3 kDa Cluster

(2011) Amala Dass   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Au36(SPh)23Nanomolecules

(2011) Praneeth Reddy Nimmala et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Au102(p-MBA)44Nanoparticles

(2011) Yael Levi-Kalisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organogold Clusters Protected by Phenylacetylene

(2011) Prasenjit Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Control and Thermodynamic Selection in the Synthesis of Atomically Precise Gold Nanoclusters

(2011) Zhikun Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and Structural Characterization of an Octaneselenolate-Protected Au25Cluster

(2011) Yuichi Negishi et al.   LANGMUIR

(AuAg)144(SR)60 alloy nanomolecules

(2011) Chanaka Kumara et al.   Nanoscale

Catalytically highly active top gold atom on palladium nanocluster

(2011) Haijun Zhang et al.   NATURE MATERIALS

Real-Space Observation of Prolate Monolayer-Protected Au38 Clusters Using Aberration-Corrected Scanning Transmission Electron Microscopy

(2011) Zhi Wei Wang et al.   Small

A 58-electron superatom-complex model for the magic phosphine-protected gold clusters (Schmid-gold, Nanogold®) of 1.4-nm dimension

(2011) Michael Walter et al.   Chemical Science

The Story of a Monodisperse Gold Nanoparticle: Au25L18

(2010) Joseph F. Parker et al.   ACCOUNTS OF CHEMICAL RESEARCH

One-Pot Synthesis of Au25(SG)18 2- and 4-nm Gold Nanoparticles and Comparison of Their Size-Dependent Properties

(2010) Zhikun Wu et al.   ADVANCED FUNCTIONAL MATERIALS

Continuous modulation of electronic structure of stable thiolate-protected Au25 cluster by Ag doping

(2010) Yuichi Negishi et al.   CHEMICAL COMMUNICATIONS

Size Effect of Silica-supported Gold Clusters in the Microwave-assisted Oxidation of Benzyl Alcohol with H2O2

(2010) Yongmei Liu et al.   CHEMISTRY LETTERS

On the Structure of a Thiolated Gold Cluster: Au44(SR)282−

(2010) De-en Jiang et al.   Journal of Physical Chemistry C

MALDI Mass Analysis of 11 kDa Gold Clusters Protected by Octadecanethiolate Ligands

(2010) Risako Tsunoyama et al.   Journal of Physical Chemistry C

Vibrational Circular Dichroism of Adsorbed Molecules: BINAS on Gold Nanoparticles

(2010) Cyrille Gautier et al.   Journal of Physical Chemistry C

Thiolate-Protected Au24(SC2H4Ph)20 Nanoclusters: Superatoms or Not?

(2010) Manzhou Zhu et al.   Journal of Physical Chemistry Letters

Size Focusing: A Methodology for Synthesizing Atomically Precise Gold Nanoclusters

(2010) Rongchao Jin et al.   Journal of Physical Chemistry Letters

Site-Specific and Size-Dependent Bonding of Compositionally Precise Gold−Thiolate Nanoparticles from X-ray Spectroscopy

(2010) Mark A. MacDonald et al.   Journal of Physical Chemistry Letters

Counting the Atoms in Supported, Monolayer-Protected Gold Clusters

(2010) Z. W. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Interactions of O2with Small Gold Cluster Anions (Aun−,n= 1−7): Chemisorption vs Physisorption

(2010) Wei Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structural Determination of Multidentate 2,3-Dithiol-Stabilized Au Clusters

(2010) Zhenghua Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Exchange Reactions on Au38and Au40Clusters: A Combined Circular Dichroism and Mass Spectrometry Study

(2010) Stefan Knoppe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Structural Evolution of Medium-Sized Gold Clusters: Aun−(n= 27−35)

(2010) Nan Shao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chirality and Electronic Structure of the Thiolate-Protected Au38Nanocluster

(2010) Olga Lopez-Acevedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Ubiquitous Au40(SR)24Clusters from the 8 kDa Gold Clusters

(2010) Huifeng Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Structure Determination of Thiolate-Protected Au38Nanoparticles

(2010) Huifeng Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Monodisperse [Oct4N+][Au25(SR)18−] Nanoparticles, with Some Mechanistic Observations

(2010) Joseph F. Parker et al.   LANGMUIR

Isolation, structure, and stability of a dodecanethiolate-protected Pd1Au24 cluster

(2010) Yuichi Negishi et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

HCl-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to “Magic-Number” Au13 Clusters

(2010) Yukatsu Shichibu et al.   Small

Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime

(2010) Yongmei Liu et al.   ACS Catalysis

Size-Focusing Synthesis, Optical and Electrochemical Properties of Monodisperse Au38(SC2H4Ph)24 Nanoclusters

(2009) Huifeng Qian et al.   ACS Nano

Thiolated Gold Nanowires: Metallic versus Semiconducting

(2009) De-en Jiang et al.   ACS Nano

Structural Transition of Gold Nanoclusters: From the Golden Cage to the Golden Pyramid

(2009) Wei Huang et al.   ACS Nano

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25clusters on hydroxyapatite

(2009) Yongmei Liu et al.   CHEMICAL COMMUNICATIONS

General Strategy for Direct Synthesis of L10Nanoparticle Alloys from Layered Precursor: The Case of FePt

(2009) Aldo Capobianchi et al.   CHEMISTRY OF MATERIALS

Facile, Large-Scale Synthesis of Dodecanethiol-Stabilized Au38Clusters†

(2009) Huifeng Qian et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Preparation of ∼1 nm Gold Clusters Confined within Mesoporous Silica and Microwave-Assisted Catalytic Application for Alcohol Oxidation

(2009) Yongmei Liu et al.   Journal of Physical Chemistry C

What Protects the Core When the Thiolated Au Cluster is Extremely Small?

(2009) De-en Jiang et al.   Journal of Physical Chemistry C

Conversion of Polydisperse Au Nanoparticles into Monodisperse Au25 Nanorods and Nanospheres

(2009) Huifeng Qian et al.   Journal of Physical Chemistry C

Structure and Bonding in the Ubiquitous Icosahedral Metallic Gold Cluster Au144(SR)60

(2009) Olga Lopez-Acevedo et al.   Journal of Physical Chemistry C

Mass Spectrometric Identification of Au68(SR)34Molecular Gold Nanoclusters with 34-Electron Shell Closing

(2009) Amala Dass   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiolate-Protected Au20Clusters with a Large Energy Gap of 2.1 eV

(2009) Manzhou Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanocluster Size Evolution Studied by Mass Spectrometry in Room Temperature Au25(SR)18Synthesis

(2009) Asantha C. Dharmaratne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magic Numbers of Gold Clusters Stabilized by PVP

(2009) Hironori Tsunoyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiolate-Protected Au20(SR)16Cluster: Prolate Au8Core with New [Au3(SR)4] Staple Motif

(2009) Yong Pei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis

(2009) Hironori Tsunoyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrospray Ionization Mass Spectrometry of Intrinsically Cationized Nanoparticles, [Au144/146(SC11H22N(CH2CH3)3+)x(S(CH2)5CH3)y]x+

(2009) Christina A. Fields-Zinna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mass Spectrometry of Small Bimetal Monolayer-Protected Clusters

(2009) Christina A. Fields-Zinna et al.   LANGMUIR

Controlling Nanoparticles with Atomic Precision: The Case of Au144(SCH2CH2Ph)60

(2009) Huifeng Qian et al.   NANO LETTERS

Size-specific catalytic activity of platinum clusters enhances oxygen reduction reactions

(2009) Kimihisa Yamamoto et al.   Nature Chemistry

Relativistic Effects and the Unique Low-Symmetry Structures of Gold Nanoclusters

(2008) Wei Huang et al.   ACS Nano

Nanoalloys:  From Theory to Applications of Alloy Clusters and Nanoparticles

(2008) Riccardo Ferrando et al.   CHEMICAL REVIEWS

In Search of a Structural Model for a Thiolate-protected Au38 Cluster

(2008) De-en Jiang et al.   Journal of Physical Chemistry C

Highly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes

(2008) Yawen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Structure of Thiolate-Protected Au25

(2008) Jaakko Akola et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The “Staple” Motif:  A Key to Stability of Thiolate-Protected Gold Nanoclusters

(2008) De-en Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural Prediction of Thiolate-Protected Au38: A Face-Fused Bi-icosahedral Au Core

(2008) Yong Pei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanoparticle MALDI-TOF Mass Spectrometry without Fragmentation: Au25(SCH2CH2Ph)18and Mixed Monolayer Au25(SCH2CH2Ph)18−x(L)x

(2008) Amala Dass et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetically Controlled, High-Yield Synthesis of Au25Clusters

(2008) Manzhou Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]

(2008) Michael W. Heaven et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications

(2008) Nirmalya K. Chaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Correlating the Crystal Structure of A Thiol-Protected Au25Cluster and Optical Properties

(2008) Manzhou Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Microfluidic Synthesis and Catalytic Application of PVP-Stabilized, ∼1 nm Gold Clusters

(2008) Hironori Tsunoyama et al.   LANGMUIR

Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters

(2008) Mark Turner et al.   NATURE

A unified view of ligand-protected gold clusters as superatom complexes

(2008) M. Walter et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA