4.7 Article

A cyanobiphenyl containing fluorescence turn on sensor for Al3+ ion in CH3CN-water

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 208, Issue -, Pages 159-163

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2014.11.033

Keywords

Al3+ ion; Chemosensor; Fluorescent; Turn on; Schiff base

Funding

  1. Research Foundation of Selcuk University (SUBAP)

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A novel fluorescent sensor, 4'-hydroxy-3'-(((2-hydroxyphenyl)imino)methyl)-4-biphenylcarbonitrile (AAF) was synthesized and characterized by combination of H-1, C-13, APT, COSY NMR, FT-IR, and elemental analysis. The behaviors of the receptor AAF toward different metal ions were determined by UV-vis and fluorescence spectroscopy. The receptor AAF exhibited a 24-fold increase in fluorescence intensity in the presence of Al3+ over most other competitive metal ions in CH3CN-water (v/v, 1/1). (C) 2014 Elsevier B.V. All rights reserved.

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