Journal
NANO LETTERS
Volume 13, Issue 4, Pages 1429-1434Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl304304e
Keywords
Molecular spintronics; spin crossover; scanning tunneling microscopy; density functional theory
Categories
Funding
- National Science Foundation through the phase I Center for Chemical Innovation: Center for Molecular Spintronics [CHE-0943975]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0943975] Funding Source: National Science Foundation
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Scanning tunneling microscopy and local conductance mapping show spin-state coexistence in bilayer films of Fe[(H(2)Bpz(2))(2)bpy] on Au(111) that is independent of temperature between 131 and 300 K. This modification of bulk behavior is attributed in part to the unique packing constraints of the bilayer film that promote deviations from bulk behavior. The local density of states measured for different spin states shows that high-spin molecules have a smaller transport gap than low-spin molecules and are in agreement with density functional theory calculations.
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