4.2 Article

Triton-B catalyzed, efficient one-pot synthesis of carbazates

Journal

MONATSHEFTE FUR CHEMIE
Volume 139, Issue 12, Pages 1463-1466

Publisher

SPRINGER WIEN
DOI: 10.1007/s00706-008-0955-8

Keywords

Alkyl halides; Benzyltrimethylammonium hydroxide; Carbon dioxide; Substituted hydrazines; Carbazates

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A quick and efficient, one-pot synthesis of carbazates was accomplished in high yields by the reaction of various primary, secondary, and tertiary alkyl halides with a variety of substituted hydrazines using the benzyltrimethylammonium hydroxide (Triton-B)/CO2 system. The reaction conditions are mild with simpler work-up procedures than the reported methods.

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