Article
Chemistry, Physical
Wiebke Wackerow, Zeynabou Thiam, Edy Abou-Hamad, Walid Al Maksoud, Mohamed N. Hedhili, Jean-Marie Basset
Summary: The article discusses the unique catalytic properties of tungsten-hydrides supported on oxide supports, suggesting that supported tungsten-hydride complexes coexist on the support as bis-hydride and tris-hydride species.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Review
Chemistry, Organic
Md. Belal, Satavisha Sarkar, Ranga Subramanian, Abu T. Khan
Summary: Nature utilizes haloperoxidases as one of the main sources to introduce bromine atoms in organic compounds, with pioneering studies unraveling the details of vanadium dependent bromoperoxidases. Biomimicking vanadium bromoperoxidase can be used to produce bromonium ion, leading to oxidative bromination or cleavage of various organic molecules. Furthermore, the synthesis of OATB and the synthetic utility of various OATBs have been discussed, with particular emphasis on TBATB in various organic transformations.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2022)
Article
Engineering, Environmental
Wei Wang, Chun Zhan, Yajun Li, Shengqiang Xiao
Summary: Controlling the morphology of BHJ films in solution processed polymer solar cells (PSCs) is crucial for enhancing their performance. In this study, bis(5-chlorothiophen-2-yl)alkanes (BCTA-m) with varying lengths of alkane chains (m = 3, 4, 5, and 6) were used as solvent additives to fabricate inverted PM6:Y6 PSCs. It was observed that the BCTA-4 additive resulted in the highest power conversion efficiency (PCE) of 15.59% compared to other BCTA-m additives and similar to the reference additive 1-chloronaphthlene (CN, PCE = 15.62%). The BCTA-4 device showed improved exciton generation and dissociation, charge transport, and suppressed charge recombination. This work demonstrates the potential of BCTA-4 additive for high-performance inverted PSCs based on Y6-type acceptors.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Simran Chaudhary, Dariusz Kedziera, Liliana Dobrzanska
Summary: In this study, a new flexible dipodal ligand 1,3-bis[(imidazol-2-yl) thiomethyl]benzene was used to form a series of Ag(I) complexes with different coordination geometries. The presence of an amine group in the ligand facilitated the formation of hydrogen bonds.
Article
Chemistry, Inorganic & Nuclear
Holger Kohlmann
Summary: Rotational disorder and distinction between ordered and disordered ammonium atoms pose a challenge in laboratory-based X-ray powder diffraction (XRPD), especially for compounds with heavy atoms. We performed XRPD analysis on ammonium hexabromido osmate(IV), (NH4)2OsBr6, and found that it exhibits a fully ordered structure of ammonium cations from room temperature up to its decomposition temperature.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2022)
Article
Chemistry, Multidisciplinary
Vinolia Thamilarasi Maria Joseph, Sureshkumar Molagoundampalayam Venkatachalam, Priya Arun Kumar
Summary: This study investigated the adsorption capacity of surface-modified palm fruit husk towards Mo(VI) in wastewater. The results showed that the maximum adsorption of Mo(VI) occurred at pH 2.0. The adsorbent dose required for maximum adsorption was lower for wastewater than for pure aqueous solutions. Additionally, the adsorption of Mo(VI) was minimally affected by temperature.
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION
(2022)
Article
Materials Science, Multidisciplinary
Yingjun Li, Yakun Guo, Zekun Jing, Xingtao Zhao, Yuanlin Zhou, Maobing Shuai
Summary: Organic hydrogen getters have been used in large-scale applications to eliminate hydrogen and prevent embrittlement and explosion risks. However, the hydrogen absorption rate of existing getters needs improvement. This study successfully developed a 3D N-doped carbon with interconnected hierarchical pores loaded with palladium particles. The Pd/MFC/DEB getter exhibited significantly higher hydrogen uptake performance compared to a typical Pd/AC/DEB getter, making it a promising approach for hydrogen getters.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Nora May, Niloofar Bayat, Kende Attila Beres, Petra Bombicz, Vladimir M. Petrusevski, Gyorgy Lendvay, Attila Farkas, Laszlo Kotai
Summary: A hemipyridine solvate of bis(pyridine)silver(I) perchlorate was prepared and characterized by single crystal X-ray analysis and vibrational spectroscopy. The solvate structure is isomorphic with the analogous permanganate complex. The stoichiometric ratio of the monomer [Agpy(2)ClO(4)] and the solvent pyridine is 1:0.5, and the solvate pyridine occupies 18.0% of the volume of the unit cell.
Article
Thermodynamics
Pengshuai Zhang, Ruping Ge, Chunxia Jin, Jixiu Deng, Feiyang Dai, Yameng Wan, Beibei Zhang, Shuwei Yu, Xing Li, En Zhang, Lan Zhang, Lu Zhang
Summary: The mole fraction solubility of 1-HPE in twelve mono-solvent systems was determined, and various models were used to correlate its solubility. Furthermore, Hansen solubility parameters analysis and Hirshfeld surface analysis were performed, and thermodynamic properties were calculated.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2023)
Article
Chemistry, Multidisciplinary
Zohreh Bagheri Zomoorodi, Mahboubeh Masrournia, Mohamad Reza Abedi
Summary: A selective and straightforward microextraction procedure based on dispersive micro solid-phase extraction was introduced for the simultaneous separation and preconcentration of nonsteroidal anti-inflammatory drugs. Under optimized conditions, the procedure showed good linearity, enrichment factors, and low detection limits for the drugs in water samples. High recoveries and appropriate relative standard deviations were achieved when the method was applied to human urine samples for NSAIDs determination.
Article
Chemistry, Organic
Ya. P. Kuznetsov, D. A. Pitushkin, V. V. Burmistrov, G. M. Butov
Summary: A series of N,N'-(alkane-alpha,omega-diyl)bis[N'-(adamantan-1-yl)selenoureas] were synthesized in moderate to high yields by reaction between adamantan-1-yl isoselenocyanate and alkane-alpha,omega-diamines. The synthesized compounds exhibit lower melting points compared to their isosteric analogs containing urea fragments and show promise as inhibitors of human soluble epoxide hydrolase.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
M. S. Klenov, D. B. Lempert, A. A. Konnov, D. A. Gulyaev, I. A. Vatsadze, T. S. Kon'kova, Yu. N. Matyushin, E. A. Miroshnichenko, A. B. Vorobyev, Ya. O. Inozemtsev, A. V. Inozemtsev, A. N. Pivkina, A. O. Dmitrienko, V. A. Tartakovsky
Summary: This study improved the synthesis methods for 1,2-bis(3,4-dinitropyrazol-1-yl)diazene, 1,2-bis(3,5-dinitropyrazol-1-yl)diazene, and 1,2-bis(3-nitro-1,2,4-triazol-1-yl)diazene. The standard enthalpies of formation and density of these compounds were determined experimentally. The potential use of synthesized diazenes as fillers for solid composite propellants (SCPs) was investigated and compared with other propellants based on their energy characteristics.
RUSSIAN CHEMICAL BULLETIN
(2022)
Article
Crystallography
Mayokun J. Ayodele, Travis C. Green, W. A. Chathuri Warsapperuma, Malcolm D. E. Forbes, Alexis D. Ostrowski
Summary: The title compound is obtained through the reaction of copper(II) acetate with the coordinating ligand, forming a coordination polymer with a unique paddle-wheel structure. The resulting chains are held together by intramolecular hydrogen bonding and further packed by dispersion forces to create an extended three-dimensional structure.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
(2021)
Article
Multidisciplinary Sciences
Roza Al-Aqar
Summary: This article investigates the photophysical properties of a compound, showing that the absorption and emission peaks shift in different solvents due to solvent polarity. The compound is found to have fluorescent properties in various solvents, with sensitivity to solvent polarity.
BAGHDAD SCIENCE JOURNAL
(2022)
Article
Crystallography
Wei-Qiu Kan, Shi-Zheng Wen, Pu-Su Zhao
Summary: Two Ag(I)-based coordination polymers have been synthesized and characterized, showing potential as semiconductive materials with wide band gaps. The 3D supramolecular structures are constructed from a multidentate N-donor ligand and two aromatic polycarboxylate anions via hydrogen-bonding and pi-pi interactions, with intense blue-green light emission.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
(2021)
Article
Chemistry, Organic
Ehsan Ghonchepour, Constantinos G. Neochoritis, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Mohammad R. Islami, Alexander Domling
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2019)
Article
Chemistry, Organic
Yuanze Wang, Pravin Patil, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Alexander Domling
Article
Chemistry, Physical
Marlena Gryl, Katarzyna Ostrowska, Jose Enrique Barquera-Lozada, Katarzyna M. Stadnicka
JOURNAL OF PHYSICAL CHEMISTRY A
(2020)
Article
Chemistry, Multidisciplinary
Katarzyna Rzesikowska, Mateusz Jablonski, Justyna Kalinowska-Tluscik
STRUCTURAL CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Ewa Zeslawska, Justyna Kalinowska-Tluscik, Wojciec Nitek, Henryk Marona, Anna M. Waszkielewicz
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
(2020)
Article
Chemistry, Applied
Jingyao Li, Vincenzo Di Lorenzo, Pravin Patil, Angel J. Ruiz-Moreno, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Marco A. Velasco-Velazquez, Alexander Domling
ACS COMBINATORIAL SCIENCE
(2020)
Article
Chemistry, Organic
Qian Wang, Jesse Tuinhof, Kumchok C. Mgimpatsang, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Alexander Domling
JOURNAL OF ORGANIC CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Mateusz Reczynski, Dawid Pinkowicz, Koji Nakabayashi, Christian Nather, Jan Stanek, Marcin Koziel, Justyna Kalinowska-Tluscik, Barbara Sieklucka, Shin-ichi Ohkoshi, Beata Nowicka
Summary: The molecule chain exhibits a unique multiresponsive behavior to stimuli such as temperature, pressure, light, and humidity, leading to significant changes in magnetic susceptibility and color. This stimuli-responsive material can switch between two valence states and show thermal hysteresis at room temperature, as well as sensitivity to pressure and irradiation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Spectroscopy
Wojciech Pietrus, Rafal Kurczab, Rafal Kafel, Ewa Machalska, Justyna Kalinowska-Tluscik, Adam Hogendorf, Marek Zylewski, Malgorzata Baranska, Andrzej J. Bojarski
Summary: The study explores the direct and indirect effect of fluorine on hydrogen bond patterns, revealing that a fluorine substituent decreases the strength and frequency of N-H···N hydrogen bonds while increasing the acidity of CH protons, enhancing weaker interactions. Furthermore, the position of fluorine in the aromatic ring strongly influences the C-F bond length and the stability of the N-H bond.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Organic
Xin Li, Qian Wang, Qiang Zheng, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Alexander Doemling
Summary: In this study, a series of reactions were used to synthesize isoquinolin-2(1H)-yl-acetamides and isoindolin-2-yl-acetamides with high yields. These products have potential applications in receptor chemistry. The scope and limitations of these reactions were also explored.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Katarzyna Rzesikowska, Justyna Kalinowska-Tluscik, Anna Krawczuk
Summary: Computational methods, especially molecular docking-based calculations, are essential in modern drug discovery. The scoring function is a useful energy-based element in docking software for evaluating ligand-protein binding. However, the current scoring functions often lead to incorrect selection of hit molecules and poor pose prediction.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Dariusz Ciez, Aleksandra Palasz, Krzysztof Koziel, Antonii Lutsan, Justyna Kalinowska-Tluscik
Summary: Titanium(iv) enolates of cyclododecanone are used as CH-acidic units in aldol additions, leading to the formation of β-hydroxy carbonyl compounds. The reactions are carried out at low temperatures to minimize dehydration and enone formation. Unlike alkali metal enolates, titanium(iv) enolates of cyclododecanone favor syn-stereoselectivity. The stereoselectivity of the aldolization reaction depends on the size and location of substituents in the aromatic ring of benzaldehydes.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Roberto Butera, Annadka Shrinidhi, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Alexander Domling
CHEMICAL COMMUNICATIONS
(2020)
Article
Materials Science, Multidisciplinary
Ewelina Wlazlak, Justyna Kalinowska-Tluscik, Dawid Przyczyna, Piotr Zawal, Konrad Szacilowski
JOURNAL OF MATERIALS CHEMISTRY C
(2020)
Article
Chemistry, Multidisciplinary
Eman M. M. Abdelraheem, Imogen Goodwin, Shabnam Shaabani, Michel P. de Haan, Katarzyna Kurpiewska, Justyna Kalinowska-Tluscik, Alexander Domling
CHEMICAL COMMUNICATIONS
(2020)
