Journal
MOLECULAR PHYSICS
Volume 117, Issue 7-8, Pages 888-897Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268976.2018.1527409
Keywords
Dipolar relaxation; contact relaxation; coupling factor; solution DNP; NMR sensitivity
Funding
- European Cooperation in Science and Technology [CA15209]
- Ministero dell'Istruzione, dell'Universita e della Ricerca [PRIN 2012SK7ASN]
- Fondazione Cassa di Risparmio di Firenze
- Instruct-ERIC Core Centre CERM, Italy
Ask authors/readers for more resources
Overhauser dynamic nuclear polarisation (DNP) represents a potentially outstanding tool to increase the sensitivity of solution and solid state NMR experiments, as well as of magnetic resonance imaging. DNP signal enhancements are strongly linked to the spin relaxation properties of the system under investigation, which must contain a paramagnetic molecule used as DNP polariser. In turn, nuclear spin relaxation can be monitored through NMR relaxometry, which reports on the field dependence of the nuclear relaxation rates, opening a route to understand the physical processes at the origin of the Overhauser DNP in solution. The contributions of dipole-dipole and Fermi-contact interactions to paramagnetic relaxation are here described and shown to be responsible to both the relaxometry profiles and the DNP enhancements, so that the experimental access to the former can allow for predictions of the latter.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available