Journal
MOLECULAR PHYSICS
Volume 106, Issue 16-18, Pages 2001-2009Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268970802054040
Keywords
radiation transition probabilities; ions; spectroscopy; molecular physics
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The theoretical calculations of dipole moments provide reliable compact information required for the evaluation of radiative transition probabilities in the electronic states of small molecular ions. The comparison of the computed line intensities and dipole derivatives with available experimental data in neutral molecules demonstrates that they can be calculated ab initio with a precision of a few percent, hence with an accuracy sufficient for most of the experimental applications.
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