Review
Chemistry, Multidisciplinary
Jake L. Greenfield, Jonathan R. Nitschke
Summary: Metal-containing polymers, or metallopolymers, have diverse applications in various fields. The self-assembly of metal-templated subcomponents allows the formation of complex structures. The control of parameters in metallopolymers can influence their growth behavior and properties, potentially meeting specific application requirements.
ACCOUNTS OF CHEMICAL RESEARCH
(2022)
Article
Polymer Science
Heng Li, Liang Han, Qing Li, Hanjian Lai, Paco Fernandez-Trillo, Leilei Tian, Feng He
Summary: By introducing molecular chirality based on amino acid derivatives (TDAP), the morphological transformation from microspheres to helical supramolecular nanofibers with controllable handedness is achieved. The chirality of the supramolecular architectures is nullified through the coassembly of the equivalent TDAP enantiomers. The molecular detection of achiral melamine based on the R-TDAP-COOH supramolecular system is achieved through the appearance of helicity and inversion.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Review
Polymer Science
Randall A. Scanga, James F. Reuther
Summary: Significant advances have been made in the field of chiral helical polymers, with emergent properties of chiral nanoobjects derived from self-assembly and potential for new functional devices. Lessons from natural systems provide parallels and opportunities for further development in the field.
Article
Chemistry, Multidisciplinary
Zhong-Liang Gong, Yu-Wu Zhong
Summary: This research demonstrates the preparation of polymorphic helical architectures with highly efficient CPL and inverted handedness by controlling the assembly pathway of chiral emitters.
SCIENCE CHINA-CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Xihao Tang, Xiangji Liao, Xinting Cai, Jialin Wu, Xueying Wu, Qianni Zhang, Yilun Yan, Shengrun Zheng, Huawei Jiang, Jun Fan, Songliang Cai, Weiguang Zhang, Yi Liu
Summary: Two chiral covalent organic frameworks (COFs) with well-defined one-handed double-helical nanofibrous morphologies were successfully constructed using a template-free method based on the diastereoselective formation of aminal linkages. Time-dependent experiments revealed the spontaneous transformation of initial rod-like aggregates into the double-helical microstructures. The helical chirality and circular dichroism signal can be easily reversed by adjusting the amount of acetic acid during synthesis. Furthermore, the helical COF nanostructures were able to induce circularly polarized luminescence with a high luminescent asymmetric factor (g(lum)) of approximately 0.01 by transferring chirality to achiral fluorescent molecular adsorbents.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Yuxin Wang, Lin Zhao, Yibo Dai, Miao Xu, Ruilin Zhou, Bingxin Zhou, Kaijun Gou, Rui Zeng, Lu Xu, Heran Li
Summary: This study demonstrates the importance of chirality in the oral adsorption efficiency of nanocarriers. The l-CMSNs, modified with l-tartaric acid, outperformed other chiral and achiral counterparts in sequential processes including mucus permeation, mucosa bio-adhesion, cellular uptake, intestinal transport, and gastrointestinal tract retention. Furthermore, l-CMSN showed stable absorption into the blood, improved intestinal transport for the loaded drug, and enhanced bioavailability and antitumor effect.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jae-Yeon Yang, Tae Hoon Ko, Yun-Su Kuk, Min-Kang Seo, Byoung-Suhk Kim
Summary: Ordered and disordered mesoporous carbons were synthesized via self-assembly and low-temperature autoclave methods. The materials showed highly ordered hexagonal mesostructures with a uniform pore size and exhibited high specific surface area and pore volume. The electrochemical performance of the mesoporous carbon materials was excellent.
Article
Polymer Science
Zhenghui Liu, Yuan Yao, Xinfeng Tao, Jie Wei, Shaoliang Lin
Summary: Imposing chirality to supramolecular architectures is crucial for understanding and utilizing chiral nanomaterials. The self-assembly of amphiphilic chiral copolymers into helical supramolecular rods is achieved through intrachain stacking of chiral units along the main chain. The reversible supramolecular self-assembly retains sublevel chirality even when the helical appearance is destroyed.
Article
Chemistry, Multidisciplinary
Peizhao Liu, Yann Battie, Takaki Kimura, Yutaka Okazaki, Piyanan Pranee, Hao Wang, Emilie Pouget, Sylvain Nlate, Takashi Sagawa, Reiko Oda
Summary: Helical perovskite nanocrystals (H-PNCs) were grown inside nanometric helical porous silica, with their handedness determined by the templates. The H-PNCs exhibit strong induced circular dichroism (CD) and circularly polarized luminescence (CPL) signals, with high dissymmetry g-factors. The circular dichroism originates from the chiral shape of the H-PNCs, as demonstrated by simulations.
Article
Chemistry, Multidisciplinary
Zixuan Zhao, Lulu Zhang, Ying Zhao, Yanji Li, Jianbing Shi, Junge Zhi, Yuping Dong
Summary: In this study, a series of V-shaped chiral polyamides with aggregation-induced emission (AIE) properties were synthesized. The polymer P1-C6 with moderate alkyl chain length demonstrated superior AIE performance. It exhibited strong circular dichroism (CD) signals with positive Cotton effect and fluorescence quenching response specifically to Fe3+.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Biophysics
Lulu Wu, Kaijun Gou, Xianmou Guo, Yingyu Guo, Muyun Chen, Jinxin Hou, Sanming Li, Heran Li
Summary: This study investigated the effects of pH and chirality on the release of flurbiprofen, revealing that chiral mesoporous silica nanoparticles exhibited intelligent drug release behavior by responding to both chirality and pH. The chiral environment can influence the release of drugs, providing valuable insights for the design of drug delivery systems.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Sachin A. Bhat, D. S. Shankar Rao, S. Krishna Prasad, Channabasaveshwar Yelamaggad
Summary: Recent research has focused on the potential of chiral plasmonic superstructures resulting from directed self-assembly of optically active metal nanoparticles (MNPs) for various technological applications. Strategic efforts have led to the successful realization of monodisperse LC-gold NPs (LC-GNPs) self-assembling into a fluid/frozen lamellar structure exhibiting CD activity, which could play a crucial role in the development of metamaterials in the visible region.
NANOSCALE ADVANCES
(2021)
Article
Chemistry, Multidisciplinary
Liao-Yuan Yao, Lin Qin, Ziyong Chen, Jonathan Lam, Vivian Wing-Wah Yam
Summary: This study explores the importance and mechanism of chiral self-assembly and self-sorting in gold cluster systems. By introducing ligands with different chirality, unique chiral gold clusters with specific shapes were successfully synthesized. Both homochiral and heterochiral self-sorting processes were observed, as well as the transfer of chirality from ligands to gold clusters, resulting in changes in symmetry.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Environmental
Kaijun Gou, Yumei Wang, Linlin Xie, Xianmou Guo, Yingyu Guo, Jia Ke, Lulu Wu, Sanming Li, Heran Li
Summary: Chiral mesoporous silica nanoparticles (CMSNs) have unique physicochemical properties and advantages in biological behavior, making them valuable in various applications such as chiral catalysis, chiral selectivity, chiral recognition, separation, drug delivery, and medical research. Studies on CMSNs have made significant progress in synthesis, chirality origination mechanisms, structural properties, and practical applications, indicating great potential in the field of pharmaceutical science and beyond.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Li Xu, Min Guo, Chin-Te Hung, Xiao-Lei Shi, Yiwen Yuan, Xingmiao Zhang, Ren-Hua Jin, Wei Li, Qiang Dong, Dongyuan Zhao
Summary: We report a strategy for the synthesis of chiral mesoporous silica nanospheres with molecular-scale-like chirality. The functionalization of micelles with chiral amide gels leads to the growth of molecularly chiral silica sols, which self-assemble into dendritic large mesoporous silica nanospheres with molecular chirality. The resulting chiral mesoporous silica shows abundant large mesopores, high pore volumes, high surface areas, and exhibits notable optical activity. It also displays good chiral stability and exhibits significant inhibition of β-amyloid protein aggregation formation and cytotoxicity.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Zhijie Xue, Fuwei Gan, Hong Liu, Chengshuo Shen, Huibin Qiu, Bo Yang, Ping Yu
Summary: Hydrogen-bonded molecules and their dynamics play a significant role in chemistry and biology, offering versatile functionality. This study presents a method to achieve tunable helical conformation in hydrogen-bonded molecular networks on metal surfaces. The dynamics of helical conformation were investigated using scanning probe microscopy at the single-molecule level, and surface-specific hydrogen bonds were identified as the origin of this dynamic conformation. These findings provide a unique approach to molecular architecture with tunable helical conformation driven by hydrogen-bond interactions on surfaces.
Article
Chemistry, Multidisciplinary
Jinghao Wang, Chengshuo Shen, Guoli Zhang, Fuwei Gan, Yongle Ding, Huibin Qiu
Summary: The study reports a unique method to prepare pi-extended chiral nanographenes with 29 benzenoid rings and two helical breaches. The resulting chiral nanographenes are configurationally stable at 180 degrees C with globally delocalized pi-systems, nearly panchromatic absorption, intensive electronic circular dichroism signals, and deep-red circularly polarized luminescence.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Yan Sun, Yipeng Zang, Wenzhi Tian, Xujiang Yu, Jizhen Qi, Liwei Chen, Xi Liu, Huibin Qiu
Summary: This study presents a facile and scalable N-2-plasma strategy to promote the phase transformation of MoS2 nanosheets and improve the electrocatalytic performance. The plasma also facilitates Pt atom diffusion and enhances the production of the 1T phase. The resulting N,Pt-MoS2 nanosheet complexes show excellent alkaline HER activity.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Yuanfei Ding, Xueliang Wang, Miao Tang, Huibin Qiu
Summary: A facile method was developed to fabricate boron-doped carbon dot composites with full-color long lifetime RTP, which can be tailored by adjusting the mass ratios of citric acid and boric acid precursors and the pyrolysis temperature. The phosphorescence can shift from blue to red by increasing the citric acid feeding or higher pyrolysis temperature.
Article
Chemistry, Multidisciplinary
Geyu Lin, Huibin Qiu
Summary: The rapid development of continuous flow processes has led to innovations in chemical syntheses and industrial productions. Immobilizing catalysts in flow reactors can enhance efficiency and eliminate subsequent separation procedures. This article discusses the methods of incorporating catalysts in flow reactors, with an emphasis on utilizing additional supports such as inorganic materials, polymeric materials, and other specific materials for different conditions. It also explores advanced techniques for ordered micro-/nanoarrays and the application of vortex fluidic devices to inspire novel designs of supports for fluidic reactors with diverse applications.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Jiandong Cai, Ian Manners, Huibin Qiu
Summary: This study presents a strategy to assemble inorganic nanoparticles with different shapes and sizes into satellite-like structures with polymer micelles. The precise nesting of nanoparticles between the satellite building units is achieved through hydrogen bonding and self-adaptive expansion of the flexible toroidal units.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Physical
Qiuwen Liu, Qiang Liu, Yawei Wu, Renyou Zeng, Fangshu Xing, ChuChu Cheng, Huibin Qiu, Caijin Huang
Summary: This study successfully synthesized macroscopic foam materials with multimodal hierarchically porous structure by combining different methods, and found that they exhibit excellent performance in fields such as oxidation dehydrogenation.
Editorial Material
Polymer Science
Frieder Jakle, Markus Gallei, Huibin Qiu
Article
Chemistry, Multidisciplinary
Fang Wang, Chengshuo Shen, Fuwei Gan, Guoli Zhang, Huibin Qiu
Summary: Researchers have developed a general strategy to generate chiroptical materials with multicolor and signinvertible circularly polarized luminescence (CPL) through charge-transfer (CT) complexation and co-assembly. The resulting assemblies exhibit intense CPL with highly tunable emission bands and handedness. Single-crystal analysis shows that the molecular packing is alternately and asymmetrically arranged through CT interactions, leading to efficient transfer and inversion of chirality.
Article
Chemistry, Medicinal
Fuwei Gan, Peng Yang, Juncong Liang, Chengshuo Shen, Jeanne Crassous, Huibin Qiu
Summary: We describe a facile method to produce circularly polarized luminescence (CPL) from helicene racemates via supramolecular association with DNA in aqueous solution. Racemic cationic helicene derivatives are immobilized in the grooves of commercially available double-stranded right-handed DNA, and the discrimination of left- and right-handed helicenes by chiral DNA is monitored by single molecule force spectroscopy. This strategy provides a distinctive insight into the fabrication of CPL-emitting systems.
Article
Chemistry, Multidisciplinary
Fuwei Gan, Chengshuo Shen, Wenying Cui, Huibin Qiu
Summary: In this study, a new type of curved nanographene with a [1,4]diazocine core was synthesized through an unusual diradical cation mechanism and C-H arylation. The resulting nanographene showed a unique concave-convex structure that could be modulated by a helicene moiety. The [1,4]diazocine-embedded nanographene exhibited typical electron-rich characteristics and formed charge transfer complexes with tunable emissions.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Chemistry, Multidisciplinary
Yan Cui, Jingchun Wang, Juncong Liang, Huibin Qiu
Summary: Creating architectures with precise hierarchies drives the development of revolutionary functions and applications in various fields. By utilizing diverse interparticle driving motifs, such as confining templates, interactive surface ligands, and flexible shape/surface anisotropy, it is possible to organize atom-like micro- and nanoparticles into colloidal analogs of molecules. In addition, the self-regulated/adaptive co-assembly of simple unvarnished building blocks is discussed to inspire new designs of colloidal assembly strategies.
Article
Multidisciplinary Sciences
Zhao Jiang, Liangrui He, Zhiwen Yang, Huibin Qiu, Xiaoyuan Chen, Xujiang Yu, Wanwan Li
Summary: The study demonstrates a multi-ion co-sensitization strategy for achieving ultrawideband-responsive photon conversion of lanthanide nanocrystals from UV to NIR. The authors show applications for low-powered white light-based bioimaging and excitation-regulated encryption.
NATURE COMMUNICATIONS
(2023)
Article
Multidisciplinary Sciences
Na Yang, Chengshuo Shen, Guoli Zhang, Fuwei Gan, Yongle Ding, Jeanne Crassous, Huibin Qiu
Summary: Remote C-H functionalization is an important process for the conversion and utilization of arenes. A metal/template-free electrochemical strategy is developed for remote C-H functionalization in a helical system, where hydrogen atoms act as directing groups to facilitate alkoxylation. This strategy allows precise decoration of inert helicene skeletons with various alkoxy pendants. Selective decoration of a methoxy group on N-methylated aza[6]helicene leads to distinct luminescence variation upon changing solvents.
Article
Chemistry, Multidisciplinary
Xiaomin Cai, Wenzhi Tian, Zekai Zhang, Yan Sun, Lei Yang, Hongchun Mu, Cheng Lian, Huibin Qiu
Summary: A poly(2-vinylpyridine) coating with modulated coordination strength and ion conductivity is reported as an effective strategy to inhibit dendrite growth in Zn anodes. The coating promotes electrolyte wettability and rapid Zn2+ migration speed. Additionally, the use of partially quaternized P2VP further reduces the interfacial resistance, leading to a considerably low nucleation overpotential and a high ion migration speed.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Applied
Lulu Wan, Gan Ye, Yuying Chang, Zhaohan Yang, Guangming Shi, Qiuli Zhang, Jin Wang
Summary: This study developed an efficient approach to upgrade the oxidative desulfurization (ODS) performance of Zr-MOFs with proton stimulation. Experimental results showed that the introduction of protons can significantly improve the ODS efficiency. This work provides a facile and efficient strategy for enhancing the ODS performance of pristine MOFs.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Qiqi Lu, Xiu-Zhi Wei, Qi Zhang, Xinghua Zhang, Lungang Chen, Jianguo Liu, Yubao Chen, Longlong Ma
Summary: The application of Pd-M bimetallic clusters in the selective hydrogenation reaction was investigated, and the Pd0.6Ni@S-1 catalyst was found to exhibit high selectivity in the conversion of phenylacetylene to styrene. The confinement effect of zeolite inhibited over-hydrogenation and improved the stability of the catalysts. Furthermore, the solvent properties also influenced the product distribution.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Review
Chemistry, Applied
Bo Li, Lumin Hong, Changdi Jing, Xianyang Yue, Huabo Huang, Qianqian Jiang, Jianguo Tang
Summary: MOF materials with adjustable pore structure and polymetallic sites have been explored as electrocatalysts for OER. Bimetallic materials show higher electrocatalytic activity than monometallic materials, while carbon-coated and doped MOF catalysts exhibit stable and good OER activity. The synergistic interaction between polymetallic active sites effectively improves the intrinsic activity of MOF on OER.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Shichun Gu, Ruyi Wang, Junxiong Zhang, Hairong Dong, Liping Deng, Xue Wang, Yapeng He
Summary: In this study, monodispersed hollow mesoporous organosilica nanospheres with controlled core cavity and mesoporous shell were successfully synthesized. These hollow nanospheres showed a high adsorption capacity for Pb2+ in water solution and exhibited acceptable recycling and stability.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Lucie Havelkova, Bogdana Bashta, Michaela Vankova, Jiri Zednik, Jiri Brus, Jan Svoboda, Alice Vagenknechtova, Jan Sedlacek
Summary: An atom-economic one-step chain-growth coordination homopolymerization providing high yields of functionalized hyper-cross-linked polyacetylenes with a permanent micro/mesoporous texture and a BET area of up to 1062 m2/g is reported. The homopolymerization is highly compatible with the heteroatom groups of the monomers and allows the preparation of well-defined porous networks with a wide spectrum of univalent groups.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Shirui Pang, Yuxin Liu, Zhe Zhang, Yuxin Li, Chunguang Li, Zhan Shi, Shouhua Feng
Summary: This study focuses on using a functional separator to suppress the shuttle effect of soluble lithium polysulfides in Li-S batteries. It is found that the functionalized sulfonic acid group not only accelerates the conduction of lithium ions, but also repels polysulfide anions through electrostatic interactions. The performance of the batteries is significantly improved with the use of this functionalized separator.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Pingping Li, Lei Han, Donghun Kim, Kemal Celebi
Summary: This study presents a fast synthetic strategy for the preparation of high-quality platelike MFI crystals using a thin-wall tubular reactor. The strategy is efficient, time-saving, and can be optimized, making it applicable to the preparation and optimization of other important materials.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Haitao Yin, Wei Wang, Yuxin Li, Hu Wen, Shuang Chen, Nanzhe Jiang
Summary: This study presents a template-free and solid-state-like crystallisation method for the synthesis of ZSM-5 zeolite, which can be scaled-up in production. Mechanical mixing of starting material components improves the dispersion of materials, leading to ZSM-5 zeolite with high crystallinity and size uniformity.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Congli Li, Jiang Wang, Zhenfei Wang, Jinxiang Dong, Qi Shi
Summary: This study investigates the evolution and autoreduction behavior of Cu species in CuCl/NaY adsorbent during vacuum thermal activation. It is found that Cu species migrate from supercages to the nearby plane of the six-membered ring connecting the supercage and sod cage during vacuum activation. At 150 degrees C, vacuum autoreduction occurs, resulting in the formation of Cu+Cl- species. The results provide reference for the preparation of pi-complex adsorbents.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Irena Khatrin, Iman Abdullah, Alan J. Mccue, Yuni K. Krisnandi
Summary: Hierarchical porous system with two types of mesopores provides a solution to the diffusion limitation in conventional zeolites. Cobalt oxide impregnated hierarchical ZSM-5 zeolite samples with intra- and inter-crystalline mesopores were synthesized using two different strategies. The physicochemical properties of the modified catalysts were analyzed, revealing distinct features given by the two mesoporous configurations. Catalytic activity analysis showed that Co-oxide/ZSM-5 with inter-crystalline mesopores exhibited higher activity in methane partial oxidation reaction compared to Co-oxide/ZSM-5 with intra-crystalline mesopores.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Nataliia Reinders, Martin Durovic, Pavla Honcova, Zaneta Dohnalova, Jana Luxova, Stanislav Slang, Jhonatan Rodriguez-Pereira, Petra S. Sulcova
Summary: This study presents a new method for preparing a microporous Ni2P/C catalyst with high catalytic activity. The redox reaction and carbon matrix formation during high-temperature treatment contribute to the stability and activity of the catalyst. Experimental and analytical results suggest that the microporous structure of the composite plays a crucial role in its catalytic performance. These findings are important for practical applications of efficient hydrogen production by water electrolysis.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Ana Raquel Bertao, Viktoriya Ivasiv, Cristina Almeida-Aguiar, Patricia R. Correia, Antonio M. Fonseca, Manuel Banobre-Lopez, Fatima Baltazar, Isabel C. Neves
Summary: This study developed a zeolite-based delivery system (ZDS) using silver and 5-Fluorouracil as antimicrobial and antineoplastic agents. The ZDS was characterized and its antimicrobial properties were investigated, showing better antibacterial effectiveness for the ZDS containing both silver and 5-FU.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Naonobu Katada, Nobuki Ozawa, Etsushi Tsuji, Keigo Kanehara, Akiho Otsuka, Taiga Sakamoto, Kirari Umezawa, Hitoshi Matsubara, Satoshi Suganuma, Momoji Kubo
Summary: First principles calculations were used to investigate the pathway for methylation of benzene with methane catalyzed by MFI type zeolite-supported Co species. The strong adsorption of benzene on Co is found to lower the activation energy for methane dissociation and promote the formation of toluene precursor. The activation energy of methane dissociation is also affected by the Al-Al distance.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Yuan Liu, An T. Ta, Kyoung Chul Park, Shenyang Hu, Natalia B. Shustova, Simon R. Phillpot
Summary: We use density functional theory to investigate the interactions of cerium, americium, and curium cations with crown ethers. Our results demonstrate that crown ethers can capture cerium, americium, and curium ions, and modifying the crown ether structure by substituting nitrogen atoms for oxygen atoms significantly increases their binding energies with radionuclides.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
Article
Chemistry, Applied
Zhengwu Peng, Shixing Wang, Yihui Wu, Xiang Liu, Hongliang Liu, Dekun Zhang, Likang Fu
Summary: An efficient adsorbent for recovery of germanium was prepared and characterized in this study. The adsorption behavior of Ge(IV) on the adsorbent was analyzed, and the results showed that it follows pseudo-secondary kinetic model and Langmuir isotherm model. The adsorbent exhibited good anionic anti-interference ability and can still maintain high adsorption efficiency after repeated adsorption.
MICROPOROUS AND MESOPOROUS MATERIALS
(2024)
