4.7 Article

The microdetermination of thallium by ICP-AES after previous preconcentration on modified silica.: Comparison with integrated-platform graphite atomic absorption spectrometry

Journal

MICROCHIMICA ACTA
Volume 162, Issue 1-2, Pages 127-132

Publisher

SPRINGER WIEN
DOI: 10.1007/s00604-007-0838-4

Keywords

thallium; ICP-AES; preconcentration on Silica C18; cationic surfactants; integrated-platform graphite AAS

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The extensively used technique of ICP-AES determination of thallium at optimal lines 190.864(1) nm and 190.864(2) nm in different orders n(1) = 135 and n(2) = 136 shows just limited sensitivity. Thus, (TlCl4)-Cl-III - was preliminarily separated and pre-concentrated on modified silica C18 in the form of ion associate with various cationic surfactants. The surfactant Zephyramine with 0.1 M HCl served as a sorbent surface activator during quantitative sorption of 5-20 mu g of thallium(III) from 15-1000 mL of aqueous solutions. The subsequent elution with 96% ethanol and the final determination with ICP were carried out after evaporating the solvent. Limited interference by SO42-, NO3-, Cl-, Na+, K+, Ca2+, Mg2+, Al3+ and Fe3+ during the sorption was observed. The above procedure is applicable for the determination of thallium in surface and mineral waters. The use of PdMg(NO3)(4) or NH4VO3 modifiers and Zeeman splitting for the sample background elimination with the integrated-platform graphite AAS technique at 276.8 nm was found to be suitable for the direct determination of thallium(I) up to 30 ng in the presence of the following species: large amounts of chlorine, 100 fold excess of NO3-, SO42-, Ca2+, Mg2+, K+, Al3+ and Fe3+. The temperature program starting by stepwise drying between 90 and 110 degrees C followed by pyrolysis at 700 degrees C and the atomisation at 1700 degrees C was optimized this way. This method can be applied for the determination of thallium in urine and spruce needles.

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