Ultrasound-assisted treatment of palm oil samples for the determination of copper and lead by stripping chronopotentiometry

The concentration of trace metals in vegetable oils is an important criterion for the assessment of oil qualities with regard to freshness, keeping properties, storage and their influence on human nutrition and health. in this work, an effective and simple method for the determination of copper and lead in palm oil by stripping chronopotentiometry (SCP) is proposed. The metal ions were concentrated as their amalgams on the glassy carbon surface of a working electrode that was coated with a thin mercury film, An ultrasonic bath was used for the extraction of copper and lead from eleven oil samples using a 1:1 (v/v) mixture of concentrated hydrochloric acid and hydrogen peroxide. Efficient extraction of copper and lead (similar to 100%) was attained after 60 min of ultrasonic pre-treatment. A good correlation between the amount of sample and the time necessary for complete liberation of the metals was observed. The accuracy of the method was evaluated by means of a reference sample of skim milk powder containing trace elements (BCR 151). Quantitative analysis was carried out by the method of standard additions. Good linearity was obtained in the range of the concentrations examined. Detection limits of 13 and 50 ng g(-1) were found for Cu and Pb, respectively, in the palm oil samples. The average values found for the palm oil samples analyzed were in the range of <0.013-2.67 mu g g(-1) for copper and <0.050-1.82 mu g g(-1) for lead. The palm oil samples were also analyzed by graphite furnace atomic absorption spectrometry (GFAAS), demonstrating a very good correlation between the results. (C) 2008 Elsevier B.V. All rights reserved.