4.1 Article

The Ksar Ghilane 002 shergottite-The 100th registered Martian meteorite fragment

Journal

METEORITICS & PLANETARY SCIENCE
Volume 48, Issue 3, Pages 493-513

Publisher

WILEY
DOI: 10.1111/maps.12074

Keywords

-

Ask authors/readers for more resources

We report on the discovery of a new shergottite from Tunisia, Ksar Ghilane (KG) 002. This single stone, weighing 538g, is a coarse-grained basaltic shergottite, mainly composed of maskelynitized plagioclase (approximately 52 vol%) and pyroxene (approximately 37 vol%). It also contains Fe-rich olivine (approximately 4.5 vol%), large Ca-phosphates, including both merrillites and Cl-apatites (approximately 3.4 vol%), minor amounts of silica or SiO2-normative K-rich glass, pyrrhotite, Ti-magnetite, ilmenite, and accessory baddeleyite. The largest crystals of pyroxene and plagioclase reach sizes of approximately 4 to 5mm. Pyroxenes (Fs2696En550Wo241). They typically range from cores of about Fs29En41Wo30 to rims of about Fs68En14Wo17. Maskelynite is Ab4149An3958Or17 in composition, but some can be as anorthitic as An93. Olivine (Fa9196) occurs mainly within symplectitic intergrowths, in paragenesis with ilmenite, or at neighboring areas of symplectites. KG 002 is heavily shocked (S5) as indicated by mosaic extinction of pyroxenes, maskelynitized plagioclase, the occurrence of localized shock melt glass pockets, and low radiogenic He concentration. Oxygen isotopes confirm that it is a normal member of the SNC suite. KG 002 is slightly depleted in LREE and shows a positive Eu anomaly, providing evidence for complex magma genesis and mantle processes on Mars. Noble gases with a composition thought to be characteristic for Martian interior is a dominant component. Measurements of 10Be, 26Al, and 53Mn and comparison with Monte Carlo calculations of production rates indicate that KG 002 has been exposed to cosmic rays most likely as a single meteoroid body of 3565cm radius. KG 002 strongly resembles Los Angeles and NWA 2800 basaltic shergottites in element composition, petrography, and mineral chemistry, suggesting a possible launch-pairing. The similar CRE ages of KG 002 and Los Angeles may suggest an ejection event at approximately 3.0Ma.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.1
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Environmental

Modelling and simulation of catalytic ammonia decomposition over Ni-Ru deposited on 3D-printed CeO2

Ilaria Lucentini, German Garcia Colli, Carlos Luzi, Isabel Serrano, Lluis Soler, Nuria J. Divins, Osvaldo Miguel Martinez, Jordi Llorca

Summary: The study focuses on preparing 3D-printed ceria structures via robocasting, impregnating them with Ni and Ru for catalytic decomposition of ammonia, validating the proposed model through simulations and experimental data comparison.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Low-temperature partial oxidation of methane over Pd-Ni bimetallic catalysts supported on CeO2

Shiva Fazlikeshteli, Xavier Vendrell, Jordi Llorca

Summary: Monometallic Pd and Ni and bimetallic Pd-Ni catalysts supported on CeO2 were prepared and tested for syngas production by the partial oxidation of methane. Bimetallic Pd-Ni/CeO2 catalysts exhibited higher methane conversion and syngas yield compared to monometallic Ni/CeO2 and Pd/CeO2. The bimetallic catalysts prepared by ball milling showed syngas production at lower temperatures. Various preparation parameters were examined, and the best performance was achieved with a bimetallic catalyst prepared at 50 Hz for 20 min, containing only 0.12 wt% Pd and 1.38 wt% Ni. Stability tests demonstrated superior stability for mechanochemically prepared bimetallic Pd-Ni/CeO2 catalysts. The results suggest that the impressive dispersion of metal species and strong interaction with the CeO2 surface contribute to the improved performance.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Article Geochemistry & Geophysics

Isotopically Heavy Micrometeorites-Fragments of CY Chondrite or a New Hydrous Parent Body?

M. D. Suttle, L. Folco, Z. Dionnet, M. Van Ginneken, T. Di Rocco, A. Pack, M. Scheel, A. Rotundi

Summary: In this study, 3D images of micrometeorite interiors were obtained using tomography, and the textures in unmelted micrometeorites were linked to known chondrite groups. In addition to ordinary chondrites, CR and CM chondrites, two micrometeorites derived from an anomalous O-16-poor source were identified, representing hydrated carbonaceous chondrite material possibly from a new group or from CY chondrites.

JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS (2022)

Article Geochemistry & Geophysics

In-Situ and Triple Oxygen Isotope Characterization of Seafloor Drilled Cherts: Marine Diagenesis and Its Bearing on Seawater Reconstructions

David O. Zakharov, Johanna Marin-Carbonne, Andreas Pack, Tommaso Di Rocco, Martin Robyr, Torsten Vennemann

Summary: This study investigates the influence of marine diagenesis on the isotope composition of cherts obtained from deep-sea drilling. The results reveal significant ambiguity in interpreting seawater evolution due to the complex effect of diagenesis. The study also highlights the correlation between isotopic composition and petrographic features of cherts.

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS (2023)

Article Biochemistry & Molecular Biology

Nanoshaped Cerium Oxide with Nickel as a Non-Noble Metal Catalyst for CO2 Thermochemical Reactions

Jaroslaw Serafin, Jordi Llorca

Summary: In this study, four different nanoshapes of cerium dioxide were prepared and decorated with various metals. Adding metals to cerium dioxide enhanced its ability to release oxygen and reduce CO2. The best catalyst, 2% Ni/CeO2-rods prepared by ball milling, showed the highest CO2 splitting value (412 μmol/g(cat)) and confirmed its good redox ability with H-2 consumption (453.2 μmol/g(cat)).

MOLECULES (2023)

Review Chemistry, Physical

When ionic liquids meet diazonium salts to generate thin layers of modified surfaces

Quentin Lenne, Zaynab Atyf, Jalal Ghilane

Summary: Immobilizing thin organic layers with specific functional groups onto materials is a key strategy for controlling properties and developing task-specific surfaces. Recent attention has been given to the combination of ionic liquids (ILs) and diazonium compounds to create organized interfaces. This review explores the grafting procedures of diazonium in IL, including electrochemical assisted grafting, and highlights the properties of the resulting layers and the advantages of using IL as a grafting medium.

CURRENT OPINION IN ELECTROCHEMISTRY (2023)

Article Nanoscience & Nanotechnology

Bimetallic NiFe Nanoparticles Supported on CeO2 as Catalysts for Methane Steam Reforming

Andrea Braga, Marina Armengol-Profitos, Laia Pascua-Sole, Xavier Vendrell, Lluis Soler, Isabel Serrano, Ignacio J. Villar-Garcia, Virginia Perez-Dieste, Nuria J. Divins, Jordi Llorca

Summary: The catalytic performance and mechanism of Ni-Fe nanocatalysts supported on CeO2 for methane steam reforming were investigated. It was found that the dry ball milling method resulted in a higher amount of defective carbon on the surface of the catalysts, which improved their coke resistance.

ACS APPLIED NANO MATERIALS (2023)

Article Chemistry, Inorganic & Nuclear

Sustainable Solvent-Free Selective Oxidation of Benzyl Alcohol Using Ru(0) Supported on Alumina

Eleonora Aneggi, Filippo Campagnolo, Daniele Zuccaccia, Walter Baratta, Jordi Llorca, Alessandro Trovarelli

Summary: This study investigates the solvent-free oxidation of benzyl alcohol using air as an oxidant in the presence of ruthenium supported on alumina and zirconia. The catalyst shows good activity and complete selectivity, meeting the requirements for atom economy and environmental sustainability. The materials are stable and maintain high activity after recycling.

INORGANICS (2023)

Article Chemistry, Multidisciplinary

Ni-Mg/Al Mixed Oxides Prepared from Layered Double Hydroxides as Catalysts for the Conversion of Furfural to Tetrahydrofurfuryl Alcohol

Abdulaziz Aldureid, Daniel Montane, Jordi Llorca, Francesc Medina

Summary: Ni-Mg/Al mixed oxide catalysts derived from LDHs exhibited excellent performance in the one-pot production of tetrahydrofurfuryl alcohol (TFA) from furfural (FF).

CHEMISTRY-SWITZERLAND (2023)

Article Chemistry, Physical

X-ray photoelectron spectroscopy (XPS) study of surface oxidation of UO2 doped with Gd2O3 at different temperatures and atmospheres

Sonia Garcia-Gomez, Javier Gimenez, Ignasi Casas, Jordi Llorca, Joan De Pablo

Summary: The influence of GdIII doping on the surface oxidation of UO2 was investigated in situ by XPS. It was found that doping UO2 with Gd2O3 completely inhibited the oxidation of UO2 in absence of porosity. However, for porous samples, the oxidation of UO2 in presence of Gd2O3 depended strongly on the surrounding gas atmosphere.

APPLIED SURFACE SCIENCE (2023)

Article Geochemistry & Geophysics

A Dual Inlet System for Laser Spectroscopy of Triple Oxygen Isotopes in Carbonate-Derived and Air CO2

David Bajnai, Andreas Pack, Fiorella Arduin Rode, Malte Seefeld, Jakub Surma, Tommaso Di Rocco

Summary: This article describes an adaptable dual inlet system and laser spectroscopy technique for accurate measurement of the triple oxygen isotope composition, which can be applied to the study of air CO2 and carbonates.

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS (2023)

Article Chemistry, Multidisciplinary

Tuning Ni-Pyrazolate Frameworks by Post-Synthetic Fe-Incorporation for Oxidase-Mimicking H2O2 Activation

Nuria Martin, Francisco G. Cirujano, Eduardo Garcia-Verdugo, Jordi Llorca, Enrique del Rio, Ignacio Jimenez-Morales, Adrian Bogeat-Barroso, Elena Lopez-Maya, Mayra G. Alvarez

Summary: The introduction of iron ionic sites by metal exchange improves the activity of nickel materials and enables control over hydrogen peroxide activation.

CHEMPLUSCHEM (2023)

Article Nanoscience & Nanotechnology

Preformed Pt Nanoparticles Supported on Nanoshaped CeO2 for Total Propane Oxidation

Shasha Ge, Yufen Chen, Xuan Tang, Yali Shen, Yang Lou, Li Wang, Yun Guo, Jordi Llorca

Summary: In this study, Pt nanoparticles with different morphologies were loaded on CeO2 catalysts to investigate their effect on the oxidation of propane. The Pt/CeO2 catalyst with {111} facets showed higher catalytic activity compared to the Pt/CeO2 catalyst with {110} and {100} facets. XPS and DRIFTS analysis revealed that the excellent performance of Pt/CeO2 catalyst with {111} facets is attributed to the prevalence of metallic Pt species, which promotes C-C bond cleavage and facilitates the removal of surface formate species. The findings of this study provide insights into the mechanism of propane oxidation on different nanoshaped Pt/CeO2 catalysts.

ACS APPLIED NANO MATERIALS (2023)

Article Multidisciplinary Sciences

Study of the catalytic wet air oxidation of p-hydroxybenzoic acid on a fresh ruthenium catalyst supported by different oxides

Tijani Hammedi, Rahma Bensouilah, Abdelkader Ouakouak, Jordi Llorca, Francisco Medina Cabello, Zouhaier Ksibi

Summary: This study investigated the catalytic wet air oxidation of p-hydroxybenzoic acid using Ru-based catalysts supported on various materials. The physicochemical properties of the catalysts were analyzed using various characterization techniques. The presence of cerium was found to enhance the catalytic activity by increasing the surface-active oxygen through a redox process.

HELIYON (2023)

Article Chemistry, Inorganic & Nuclear

Oxidative dissolution mechanism of both undoped and Gd2O3-doped UO2(s) at alkaline to hyperalkaline pH

Sonia Garcia-Gomez, Javier Gimenez, Ignasi Casas, Jordi Llorca, Joan De Pablo

Summary: The dissolution rates of non-doped UO2 and UO2 doped with Gd2O3 were studied under different pH conditions. It was found that non-doped UO2 had a low dissolution rate under high alkaline conditions but increased significantly when the pH decreased to 9. XPS analysis confirmed the effect of bicarbonate on the dissolution of UO2. The doping of Gd2O3 did not affect the dissolution rates, and it was attributed to the retardation of U(v) oxidation by gadolinium.

DALTON TRANSACTIONS (2023)

No Data Available