4.2 Article

Metathesis of azomethine imines in reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with (het)arylidenemalononitriles

Journal

MENDELEEV COMMUNICATIONS
Volume 23, Issue 1, Pages 34-36

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2013.01.012

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Funding

  1. Russian Foundation for Basic Research [09-03-01091]
  2. Russian Academy of Sciences

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Ring opening in 6-aryl-1,5-diazabicyclo[3.1.0]hexanes gives cyclic azomethine imines which are prone to exchange of arylidene moiety with (het)arylidenemalononitriles to form the metathesis products being new azomethine imines. These species were fixed as pyrazolines due to the 1,4-H shift or trapped by dimethyl acetylenedicarboxylate or CS2.

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