Journal
MENDELEEV COMMUNICATIONS
Volume 23, Issue 4, Pages 206-208Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2013.07.009
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- Russian Foundation for Basic Research [13-03-00153]
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Ionic liquids facilitate regio- and stereoselective [3+2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated catalytically from 6-Ar-1,5-diazabicyclo[3.1.0]hexanes in the presence of BF3 center dot Et2O. The similar reaction is possible in MeCN only for azomethine imine with Ar = 2,4-(MeO)(2)C6H3 to give a mixture of two diastereomers.
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