4.2 Article

The first example of the Schmidt reaction in ionic liquids

Journal

MENDELEEV COMMUNICATIONS
Volume 20, Issue 6, Pages 335-336

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ELSEVIER
DOI: 10.1016/j.mencom.2010.11.011

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Funding

  1. Merck KGaA
  2. Russian Academy of Sciences

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The Schmidt reaction of aryl methyl ketones in ionic liquids (optimally in 1-ethyl-3-methylimidazolium triflate with CF3SO3H additive) proceeds at 40 degrees C within 10-30 h to give the corresponding acetanilides in good yields.

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