4.2 Article

Diaziridine ring expansion in 6-aryl-1,5-diazabicyclo[3.1.0]hexanes on treatment with nitriles assisted by ionic liquids

Journal

MENDELEEV COMMUNICATIONS
Volume 18, Issue 4, Pages 207-208

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ELSEVIER
DOI: 10.1016/j.mencom.2008.07.013

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Funding

  1. Presidium of the Russian Academy of Sciences

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The ionic-liquids-assisted insertion of activated nitriles into the diaziridine ring of 6-aryl- 1,5-diazabicyclo[3.1.0]hexanes catalysed with BF3 center dot Et2O provides a simple method for the preparation of 1-aryl-6,7-dihydro-1H,5H-pyrazolo[1,2-a][1,2,4]triazoles.

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