Structural, optical and ferromagnetic properties of Cr doped TiO2 nanoparticles

Cr doped TiO2 nanoparticles are prepared with three different concentrations of chromium, 1.5%, 3.0% and 4.5 mol% respectively. Doping decreases the crystallinity and increases the width of the X-ray diffraction peak. The Raman active E-g peak of TiO2 nanoparticles become asymmetric and shifted to higher energy on doping of 4.5% chromium. Electron paramagnetic resonance spectra reveal the presence of Cr3+ in the host TiO2 matrix. The absorption spectra of Cr doped TiO2 nanoparticles contain absorption peaks corresponding to d-d transition of Cr3+ in octahedral coordination. Most of the visible emission peaks are due to the electrons trapped in the oxygen vacancy centers. Undoped TiO2 nanoparticles show diamagnetism at room temperature while all chromium doped samples show ferromagnetism. The magnetization of the doped samples increases at 1.5% and 3.0% and decreases at 4.5%. The ferromagnetism arises owing to the interaction of the neighboring Cr3+ ions via oxygen vacancies. The decrease of magnetization at the highest doping is possibly due to the antiferromagnetic interactions of Cr3+ pairs or due to Cr3+-O2--Cr3+ superexchange interaction in the lattice. (C) 2013 Elsevier B.V. All rights reserved.