4.7 Article Proceedings Paper

Electron energy-loss spectroscopy study of NiTi shape memory alloys

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2006.12.227

Keywords

NiTi shape memory alloys; Ni4Ti3 precipitate; composition; EELS; Young's modulus

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Electron energy loss spectroscopy (EELS) investigations were carried out on NiTi shape memory alloys. The composition of lens-shaped precipitates is determined to be Ni4Ti3 by model-based EELS quantification, and the Ni-depleted zone in the B2 matrix surrounding the Ni4Ti3 precipitates was quantified. The Young's modulus Y-m of the B2 matrix with 51 at.% Ni and the Ni4Ti3 precipitates was evaluated to be about 124 and 175 GPa, respectively. The intensity of the Ni L-3 edge for the precipitate is slightly higher than that for the B2 phase. (C) 2007 Elsevier B.V. All rights reserved.

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