Strontium PVC-membrane sensor based on 2-[(2-mercaptophenylimino)methyl]phenol

The 2-[(2-mercaptophenylimino)methyl]phenol (MPMP) was used as an excellent ionophore in the construction of a Sr2+ PVC-based membrane sensor. The best performance was obtained with a membrane composition of 30% poly(vinyl chloride), 62% nitrobenzen (NB), 5.5% MPMP and 2.5% sodium tetraphenyl borate (NaTBP). This sensor demonstrates a good selectivity and sensitivity towards the strontium ion for many cations, including alkali, alkaline earth, transition and heavy metal ions. The sensor revealed a great enhancement in selectivity coefficients for strontium ions in comparison with the previously reported strontium sensors. The proposed sensor exhibits a Nernstian behavior (with a slope of 29.6 +/- 0.3 mV per decade) for the concentration range of (1.0 x 10(-6) -1.0 x 10(-1) M) with a detection limit of 5.5 x 10(-7) M (48.2 ng/mL). It illustrates a relatively fast response time in the whole concentration range (< 10 s) and it can be used for at least 10 weeks in a pH range of 2.8-9.6. The developed sensor was successfully used as an indicator electrode in the Sr(II ) titration with EDTA and the Sr2+ ion recovery from binary mixtures. (C) 2007 Elsevier B.V. All rights reserved.