Room-temperature ferromagnetism of Fe-doped TiO2 nanoparticles driven by oxygen vacancy

A series of Ti1-xFexO2-delta (0 <= x <= 0.03) nanoparticles (NPs) were synthesized by sol-gel route. The NPs had a size distribution in the range of 15-40 nm and were identified as the anatase TiO2 by X-ray diffraction (XRD) and Raman analysis. XRD, selected area electron diffraction, Raman and Mossbauer analysis ruled out the signature of Fe-cluster or any other oxides of Fe. The redshifting of the band edge emission peak observed in UV-vis absorption studies further confirmed the doping of Fe ions in the TiO2 lattice. Raman studies show the shifting and broadening in E-g(1) and E-g(3) modes with Fe doping. It suggested that the activation of ferromagnetism with increasing Fe doping concentration was related to the oxygen vacancy defects. The presence of such defects was further confirmed from electron paramagnetic resonance (EPR) measurements. The observed ferromagnetism is interpreted in terms of bound magnetic polaron (BMP) model. (C) 2012 Elsevier Ltd. All rights reserved.