Study on intercalation of ionic liquid into montmorillonite and its property evaluation

Present study report fabrication of a solid liquid intercalated compound using montmorillonite and ionic liquid [IL; 1-Butyl-3-methylimidazolium tetrafluoroborate; ([BMIM][BF4])]. The intercalation of IL into the interlayer of montmorillonite was revealed by swelling behavior measured by X-ray diffraction (XRD) and cation exchange capacity (CEC). The crystal swelling structure of intercalation compound was further evidenced by transmission electron microscope (TEM). From these results, the arrangement of [BMIM](+) ions (cationic part of IL) into the unit layer were proposed. Furthermore, the montmorillonite showed electrical conductivity with the aid of IL This demonstrates a successful attempt to fabricate a solid liquid state nano-structure compound as possible transparent electrically conducting thin film. (C) 2012 Elsevier B.V. All rights reserved.