Article
Polymer Science
Hussnain Sajjad, Leon M. Lillie, C. Maggie Lau, Christopher J. Ellison, William B. Tolman, Theresa M. Reineke
Summary: This study presents the development of tunable and degradable crosslinked-polyanhydride networks using renewably derived itaconic anhydrides and multifunctional thiols. The research demonstrates that itaconic acid can be a useful feedstock in the generation of degradable polyanhydride networks via thiol-ene photopolymerization.
Article
Chemistry, Applied
Jia Huang, Jinshuai Zhang, Guoqiang Zhu, Xixi Yu, Yun Hu, Qianqian Shang, Jianqiang Chen, Lihong Hu, Yonghong Zhou, Chengguo Liu
Summary: The development of self-healing UV-curable coatings from biorenewable resources shows good self-healing properties, high biobased contents, and high performance.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Green & Sustainable Science & Technology
Mohammad Asif Ali, Tatsuo Kaneko
Summary: The production of novel chiral dicarboxylic acids from renewable feedstock has been reported in this study. By synthesizing chiral polyamides with heterocyclic diacid monomers, it was found that the interaction between polymer chains of different chiralities affects the crystallization degree and performance of the composite.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Polymer Science
Josefine Meurer, Julian Hniopek, Jan Dahlke, Michael Schmitt, Jurgen Popp, Stefan Zechel, Martin D. Hager
Summary: The article introduces novel biobased ionomers with self-healing abilities synthesized from itaconic acid derivates, which can be produced in large quantities from biomass like corn and rice. Comprehensive investigation of their thermal and mechanical properties revealed different structure-property relationships, with the proportion of ionic groups significantly influencing self-healing efficiency. The ionomer based on itaconic acid with the lowest ionic content showed a self-healing efficiency of up to 99% at 90 degrees C in 2 hours.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Agricultural Engineering
Ricardo Rebolledo-Leiva, Maria Teresa Moreira, Sara Gonzalez-Garcia
Summary: This study conducted an environmental assessment of itaconic acid production from wheat straw using Life Cycle Assessment methodology, revealing pretreatment and fermentation stages as hotspots. Utilizing renewable energy can significantly reduce environmental impact.
BIORESOURCE TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Sandip K. Singh, Kolja Ostendorf, Markus Euring, Kai Zhang
Summary: This paper introduces a novel lignin-based adhesive synthesized through the synergistic reaction between lignin, dimethylformamide, and acrylic acid under a basic environment. The characterized adhesive shows excellent adhesive performance on various substrates and exhibits good physical-mechanical strength under neutral, acidic, or basic media. It is a versatile and universally applicable adhesive.
Article
Chemistry, Multidisciplinary
Hafezeh Nabipour, Xin Wang, Lei Song, Yuan Hu
Summary: The study focused on the development of a fully bio-based epoxy thermoset from syringaldehyde and furfurylamine, which exhibited high glass transition temperature, mechanical strength, intrinsic flame resistance, and antibacterial properties. This bio-based epoxy thermoset showed superior performance compared to petroleum-based epoxy thermosets, making it a promising green substitute for high performance applications in fire safety.
Review
Chemistry, Multidisciplinary
Siyuan Xiang, Mingqian Tan
Summary: This review discusses the origin of carbon dots (CDs) from natural sources and their impact on biology and the environment. It provides an overview of raw materials and synthesis procedures, and explores the potential applications in biomedicine as well as the risks to biomolecular function. The review also addresses the current challenges and offers future perspectives on evaluating the influence of CDs on daily life.
ENVIRONMENTAL SCIENCE-NANO
(2022)
Article
Electrochemistry
Hui Shi, Yixin Zhang, Qin Ouyang, Jianwei Hao, Xianbo Huang, Junjie Li, Xing Chen
Summary: Pyrolytic lignin and zinc borate are added to PANIA to improve its thermal stability and electrochemical performance, resulting in the fabrication of CPPZ anodes with higher char yield and optimal carbon structures. The synergic effects between PANIA, PyL, and ZB enhance thermal stability and promote the formation of conjugated ladder structures. CPPZ-700, as a sodium-ion battery anode, exhibits a reversible specific capacity of 180 mAh g(-1) at a current density of 100 mA g(-1), outperforming PANIA-based carbon anode by 120 mAh g(-1) under the same conditions.
ELECTROCHIMICA ACTA
(2022)
Article
Nanoscience & Nanotechnology
You-Yong Wang, Xiang-Qian Wang, Yuan-Qing Li, Pei Huang, Bo Yang, Ning Hu, Shao-Yun Fu
Summary: The study introduces a simple and effective method to convert natural bamboo into bamboo steel, which has high specific tensile strength, superior mechanical properties, excellent thermal insulation capability, and high dimensional stability. This strategy using green and abundant natural bamboo as raw materials is highly attractive for the sustainable development of structural engineering materials.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Plant Sciences
Aojie Shang, Kaile Yang, Yaling Lu, Qinghua Jia, Zhong Li, Guocai Ma, Jincheng Mu
Summary: This study designed a slow-released fertilizer made from biochar modified with itaconic acid, and investigated its effects on cucumber seedling growth. The results showed that this slow-released fertilizer exhibited good properties of water absorption, water retention, and slow-release behavior, and promoted the growth of cucumber seedlings.
JOURNAL OF SOIL SCIENCE AND PLANT NUTRITION
(2022)
Article
Chemistry, Multidisciplinary
Ryan A. Hackler, Kimaya Vyavhare, Robert M. Kennedy, Gokhan Celik, Uddhav Kanbur, Philip J. Griffin, Aaron D. Sadow, Guiyan Zang, Amgad Elgowainy, Pingping Sun, Kenneth R. Poeppelmeier, Ali Erdemir, Massimiliano Delferro
Summary: The novel technology of producing high-quality liquid lubricants from catalytic conversion of polyolefin waste presents a cost-effective and environmentally friendly solution for improving energy efficiency, mechanical durability, and reducing wear and friction in transportation applications.
Article
Biotechnology & Applied Microbiology
Lanxin Rong, Lin Miao, Shuhui Wang, Yaping Wang, Shiqi Liu, Zhihui Lu, Baixiang Zhao, Cuiying Zhang, Dongguang Xiao, Krithi Pushpanathan, Adison Wong, Aiqun Yu
Summary: This study developed a microbial cell factory that utilizes waste cooking oil as raw material for the production of itaconic acid. Through gene expression and overexpression, the production yield was significantly improved, achieving a high IA titer in a 5 L bioreactor.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2022)
Article
Engineering, Chemical
Sumana Brahma, Kothandaraman Ramanujam, Ramesh L. Gardas
Summary: In this study, bioderived high surface area activated carbons were synthesized and nitrogen-doped activated carbon was derived from a nitrogen-enriched ionic liquid and activated carbon mixture. The nitrogen-doped activated carbon showed high specific capacitance and specific energy, indicating its potential as an electrode material for supercapacitor applications.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Automation & Control Systems
Oyewole Adedipe, Victor Sunday Aigbodion, Nicholas Agbese Agbo, Sunday Albert Lawal, Oyebola Wahab Akanni Oyeladun, James Baba Mokwa, Emmanuel Toi Dauda
Summary: The surface hardening of mild steel was investigated by carburization using periwinkle shell nanoparticles (PWSnp) and coconut shell (CS). The carburization was done at temperatures of 850, 900, and 950 degrees C with varying ratios of PWSnp:CS. The results showed significant improvements in hardness, corrosion protection, and wear resistance, indicating that waste periwinkle shell and coconut shell can be effectively used for surface hardening of mild steel.
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
Kenji Takada, Katsuaki Yasaki, Sakshi Rawat, Kosuke Okeyoshi, Amit Kumar, Hideyuki Murata, Tatsuo Kaneko
Summary: Cinnamate-based polyesters were synthesized and processed into membranes which showed different photodeformation behaviors under UV light, with PdHCA membranes visibly contracting while P3HCA membranes exhibited unique photoexpansion behavior. Time-resolution infrared spectroscopy revealed trans-to-cis isomerism in the polymer main chains of the P3HCA film, leading to convex bending in UV-irradiated regions.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Green & Sustainable Science & Technology
Mohammad Asif Ali, Tatsuo Kaneko
Summary: The production of novel chiral dicarboxylic acids from renewable feedstock has been reported in this study. By synthesizing chiral polyamides with heterocyclic diacid monomers, it was found that the interaction between polymer chains of different chiralities affects the crystallization degree and performance of the composite.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Chemistry, Physical
Gargi Joshi, Kosuke Okeyoshi, Fitri Adila Amat Yusof, Tetsu Mitsumata, Maiko K. Okajima, Tatsuo Kaneko
Summary: By exploring the fluidic geometry of a liquid crystalline polysaccharide solution containing micron-sized rod and platelet units, it was found that the presence of platelet units contributes lateral capillary interactions and helps rod units form a wider self-assembled structure with high viscosity.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Saranyoo Sornkamnerd, Shuhei Sasaki, Tetsu Mitsumata, Kenji Takada, Tomohiro Okada, Shinji Ando, Tatsuo Kaneko
Summary: By synthesizing bio-polyimides using renewable materials, transparent films with high heat resistance and good electrical resistance were prepared, suitable for applications in the field of electric insulators.
Article
Engineering, Biomedical
Deyan Du, Xi Chen, Chang Shi, Zhuying Zhang, Dongjian Shi, Daisaku Kaneko, Tatsuo Kaneko, Zhen Hua
Summary: In this study, mussel-inspired epoxy bioadhesives (CSD-PEG) were successfully synthesized and exhibited high mechanical and adhesion strengths, making them promising candidates for surgical tissue repair, wound closure, and tissue engineering applications. Multiple interfacial interactions between the epoxy and catechol groups played a key role in enhancing the performance of the bioadhesives while maintaining favorable biocompatibility in vivo.
ACTA BIOMATERIALIA
(2021)
Article
Chemistry, Multidisciplinary
Yasuyoshi Funahashi, Yohei Yoshinaka, Kenji Takada, Tatsuo Kaneko
Summary: In this study, self-standing nanomembranes with high toughness were developed by spin-casting super-tough polyamides over dimethylformamide solution. These nanomembranes, which have ultra-high toughness and can be peeled off without breaking, could be applied to flexible devices in the future.
Article
Materials Science, Multidisciplinary
Isamu Saito, Leijie Wu, Mitsuo Hara, Yuka Ikemoto, Tatsuo Kaneko, Kosuke Okeyoshi
Summary: This study designs reordered polysaccharide materials with cation selectivity and anisotropic responses by controlling the drying process of an aqueous pectin dispersion. The membrane, based on the egg-box model, exhibits anisotropic responses to cations and can swell as a hydrogel. It shows potential for application in tissue engineering in physiological environments.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Physical
Yue Jiang, Shuai Wang, Weifu Dong, Tatsuo Kaneko, Mingqing Chen, Dongjian Shi
Summary: The authors developed a high-performance, degradable, and recyclable bio-based epoxy resin by reacting the lignin derivative vanillin with 4-amino cyclohexanol via Schiff base. This resin exhibited higher Young's modulus and tensile strength compared to bisphenol A epoxy. It also showed good degradation in an acidic environment and recoverability through heat treatment. Additionally, the resin could be used to prepare carbon fiber-reinforced composites, with the carbon fiber being completely recyclable. This study provides a pathway for the preparation of high-performance epoxy resin and the effective recycling of carbon fiber.
Article
Chemistry, Applied
Maninder Singh, Gargi Joshi, Han Qiang, Maiko K. Okajima, Tatsuo Kaneko
Summary: Synthetic materials cause damage over time, so the use of naturally-derived polymers for sustainable material fabrication is gaining recognition. We created hybrid hydrogel sheets using polysaccharides and nanocellulose as wound dressings. Antibacterial properties were added through silver nanoparticles in the polysaccharide blend, and the films were crosslinked via thermal annealing to avoid the use of harmful chemicals. The resulting silver nanoparticle-polysaccharide hydrogels effectively reduce bacterial viability and have potential as on-demand dressings.
CARBOHYDRATE POLYMER TECHNOLOGIES AND APPLICATIONS
(2023)
Article
Nanoscience & Nanotechnology
Jianbing Cui, Ruisheng Xu, Weifu Dong, Tatsuo Kaneko, Mingqing Chen, Dongjian Shi
Summary: Flexible and stretchable materials with ionic conductivity are crucial in the development of flexible electronic devices. In this study, a biomimetic hydrogel with strain-stiffening capability was fabricated by embedding a stiff array of poly(acrylic acid) (PAAc) in a soft polyacrylamide (PAAm) hydrogel. The resulting patterned hydrogel exhibited nonlinear mechanical properties, high strength, and protonic conductivity without the need for additional ionic salts. This hydrogel has the potential to serve as a strain sensor for monitoring human motion.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Rio Urano, Pruetsakorn Saosamniang, Tatsuo Kaneko, Mika Kawai, Tetsu Mitsumata
Summary: The relationship between the magnetorheological effect and the void ratio in a polyurethane magnetic elastomer with voids was investigated by dynamic viscoelastic measurement under a magnetic field. It was found that the void ratio had a significant impact on the storage modulus of the elastomer, allowing movement of magnetic particles within the material.
Article
Polymer Science
Jiabei Zhou, Xianzhu Zhong, Aniruddha Nag, Yang Liu, Kenji Takada, Tatsuo Kaneko
Summary: Porous polybenzimidazole derivative films were prepared using a silica template method, resulting in ultrahigh thermoresistant films with improved elongation properties and enhanced strength and hardness. Microscopic analysis confirmed the formation of pores and observed craters with swollen edges and hardened surfaces.
Article
Chemistry, Multidisciplinary
Xianzhu Zhong, Aniruddha Nag, Jiabei Zhou, Kenji Takada, Fitri Adila Amat Yusof, Tetsu Mitsumata, Kenji Oqmhula, Kenta Hongo, Ryo Maezono, Tatsuo Kaneko
Summary: In this study, ultrahigh thermoresistant bio-based terpolymers with a low dielectric constant were successfully synthesized. These materials showed great potential for various applications.
Article
Chemistry, Multidisciplinary
Kottisa Sumala Patnaik, Rajashekar Badam, Yueying Peng, Koichi Higashimine, Tatsuo Kaneko, Noriyoshi Matsumi
Summary: A highly nitrogen-doped carbon material was synthesized through easy pyrolysis of bio-based poly(2,5-benzimidazole), showing fast charging capability at 18.6 A g(-1) and excellent long-term cyclability of 3000 cycles with 90% capacity retention. Full cell studies demonstrated the commercial potential of this novel material.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Hongrong Yin, Kenji Takada, Amit Kumar, Thawinda Hirayama, Tatsuo Kaneko
Summary: An AB-type diketopiperazine monomer based on aspartame was synthesized and used in the polycondensation of high molecular weight homo-polyamides. Random DKP-based copolymers were also synthesized using various amino acids, dicarboxylic acids, and diamines. The self-assembly properties of ADKP and PA1 were studied, revealing the mechanism of particle formation and the relationship between solvent hydrogen bonding strength and morphology.