Journal
MACROMOLECULES
Volume 45, Issue 17, Pages 6864-6868Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma301293m
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Funding
- Agence Nationale de la Recherche [ANR 2010-BLAN-0802]
- Institut Universitaire de France
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New photoinitiating systems based on boron-dipyrromethene dye (bodipy)/iodonium salt and optionally tris(trimethylsilyl)silane are proposed for the polymerization of divinylether and epoxy monomers upon visible-light exposure. The presence of the silane increases the epoxide rate of polymerization and conversion. Using acrylate/vinyl ether blends, the synthesis of cross-linked polymer networks (possessing two T-g values: -11 and 111 degrees C) is also successfully achieved through concomitant cationic and radical polymerization pathways. The chemical mechanisms associated with these initiating systems are investigated by steady-state photolysis and ESR experiments.
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