Journal
MACROMOLECULES
Volume 43, Issue 24, Pages 10241-10245Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma102257a
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Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
- Manitoba Research and Innovation Fund
- University of Manitoba
- Canada Research Chairs Program
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A straightforward approach to the synthesis of electrically conducting PEDOT thin films using metastable and organic solvent processable mixtures that rapidly polymerize upon solvent evaporation is presented This one-step synthetic procedure, previously used to prepare well behaved polypyrrole and polythiophene films, has now been extended to one of the most academically/Industrially studied and commercially successful polythiophene based polymers, PEDOT The methodology can be used to synthesize smooth, uniform, homogeneous, crack and pinhole free, conducting (0 02-0 47 S/cm), and highly transmissive PEDOT films with well-defined spectroelectrochemistry by spin-coating organic-solvent processable mixtures of EDOT monomer and phosphomolybdic acid oxidant onto conductive and nonconductive glass substrates
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