Journal
MACROMOLECULES
Volume 41, Issue 21, Pages 7953-7958Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma8017537
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Funding
- Austrian Science Fund FWF [P19769-NI4]
- Mondi Packaging Release Liner Austria GmbH
- Austrian Science Fund (FWF) [P19769] Funding Source: Austrian Science Fund (FWF)
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Novel monomers with reactive diacrylamide units were developed as alternatives to common acrylate- or acryl amide-based functional groups. By using photo differential scanning calorimetry and ATR-IR spectroscopy, we were able to determine their theoretical polymerization heats and photopolymerization properties. Surprisingly, these new monomers exhibited high polymerization reactivity due to cyclopolymerization and showed self-initiating behavior under irradiation with UV light. As absorption of these photoinitiating monomers tails out at 320 nm, sensitizers were successfully employed to expand the spectral range of sensitivity.
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