Article
Materials Science, Multidisciplinary
Baku Nagendra, Giovanni Mondrone, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: The thermal release of guest molecules from PPO films with host-guest cocrystalline phases shows differences in temperatures based on the orientation of the chain axes. The control of guest release temperatures can enhance thermal stability and tailor the temperatures of active guest release in these co-crystalline phases.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Pengfu Gao, Kun Zhang, Dandan Ren, Hui Liu, Huiju Zhang, Hongru Fu, Lufang Ma, Dongsheng Li
Summary: Exploiting chirality transfer and amplification in hierarchical chiral systems remains a challenge. In this study, a pair of homochiral MOFs DCF-12 and LCF-12 were synthesized, which can act as nano-containers for introducing chromophores. The precise single crystal structures of all guest-loaded MOFs were obtained, revealing chirality transfer and achieving circularly polarized luminescence.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Binh Minh Nguyen, Markus Schmid, Johann Kirsch, Albin Cakaj, Wolfgang Bruetting
Summary: The orientation mechanism of nonpolar dyes in various conditions is studied. It is found that the shape anisotropy and temperature ratio are key factors controlling dye alignment. It is also noted that caution must be exercised when using mixed cohost systems with different glass transition temperatures, as the emitter orientation may not follow the effective glass transition temperature of the mixed host.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Organic
Jin-Fa Chen, Xiaodong Yin, Kai Zhang, Zhenhui Zhao, Songhe Zhang, Niu Zhang, Nan Wang, Pangkuan Chen
Summary: This passage describes the synthesis of highly luminescent organoboranes with dual chirality through molecular functionalization and discusses their circularly polarized luminescence and thermal robust colorimetric responses. It also explores their remarkable host-guest chemistry within pillar[5]arene-based supramolecular scaffolds for advanced chiroptical properties.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Xu Sang, Kang Zhang, Adnan Khan, Rui Xu, Yan Li, Jiaxin Yang, Ming Feng, Lisa Liu, Feng Song, Wei Huang
Summary: Electrically tunable polarized luminescence of aligned Eu(tta)(3)phen/E7 composites is achieved by the interaction between liquid crystal hosts and rare earth complex guests. The generation mechanism of the polarization effect is explored from three different aspects, including polarized energy absorption of incident light, site symmetry of Eu3+ ions, and polarized energy transfer from E7 to Eu(tta)(3)phen. The convenient control of well-aligned Eu(tta)(3)phen complex by embedding Eu(iii) complex guest in E7 host and utilizing electric field forces is confirmed.
Article
Materials Science, Multidisciplinary
Lin Zhang, Hongjun Li, Yu Yang, Deren Yang, Yuanjing Cui, Guodong Qian
Summary: In this study, a host-guest metal-organic framework (MOF) material was prepared to switch between second-harmonic generation (SHG) and two-photon-pumped (TPP) lasing in a single crystal. The use of specific alignment of nonlinear optical (NLO) building units allowed for the observation of polarized SHG and TPP lasing in a single crystal. These findings contribute to a better understanding of polarized NLO responses in MOFs and provide a new perspective for the development of versatile switching NLO materials.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Chenlin Tu, Wanhua Wu, Wenting Liang, Dongjing Zhang, Wei Xu, Shigang Wan, Wei Lu, Cheng Yang
Summary: Several gamma-cyclodextrin derivatives substituted with pyrenes at the primary rim of the CD were found to form nano-strips in aqueous solutions, with pyrene moieties interpenetrating into gamma-CD cavities. The aggregates provide a rigid chiral environment for the pyrenes, leading to significant electronic circular dichroism and circularly polarized luminescence activities.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Optics
D. Habibovic, A. Gazibegovic-Busuladzic, M. Busuladzic, D. B. Milosevic
Summary: The study investigates high-order above-threshold ionization of heteronuclear diatomic molecules using an improved molecular strong-field approximation. The photoelectron momentum distribution exhibits reflection symmetry under certain conditions. Molecular orientation and laser field parameters can affect the characteristics of the HATI spectrum.
Article
Physics, Multidisciplinary
S. Fritzsche, J. Hofbrucker
Summary: The biharmonic photoionization of atomic inner-shell electrons is an important tool for studying nonlinear light-atom interactions. By controlling the frequency and polarization of the biharmonic beams, the photoelectron angular distribution can be shaped and the resolution of ionization measurements can be enhanced. The angular distribution of the photoelectrons is sensitive to the intensity, phase difference, and temporal structure of the incoming beams. Tuning the properties of the biharmonic field allows for unprecedented control over the angular distribution and elliptical dichroism. These investigations have potential applications in extracting photoionization amplitudes or phase differences of incoming beams.
NEW JOURNAL OF PHYSICS
(2022)
Article
Optics
Tingting Liu, Hui Du, Shuhong Li, Wenjun Wang, Yunlong Liu, Dongyue Cui, Qingru Wang, Dong Zhang, Ling Zhao, Xiaochen Dong
Summary: By using blend films, the ASE and luminescence performance of BUBD-1 were enhanced due to increased Stokes shift, energy transfer efficiency, and radiation attenuation rate. Analysis based on second-harmonic generation and angle-dependent PL spectra revealed changes in molecular dipole orientation in the films. The variation in molecular dipole angle in blend films contributed to the device properties.
OPTICS AND LASER TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Fei-Hu Yu, Rui Jin, Xiaoyong Chang, Kai Li, Ganglong Cui, Yong Chen
Summary: This study reports a new class of long-persistent luminescence (LPL) materials by doping a monovalent Au-carbene complex into a boron-embedded molecular host. These materials exhibit high-efficiency photoluminescence and long lifetimes at room temperature. It is found that the Au atom promotes the population of low-lying triplet excited states, leading to afterglow luminescence. Additionally, the use of a chirality unit results in circularly polarized LPL.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Min Zhou, Bo-Wen Si, Jie Yu, Shu-Lin Cong
Summary: This study investigates the asymmetrical photoelectron angular distribution (PAD) in the ionization of NaK molecules using pump-probe femtosecond laser pulses. The results show that the carrier-envelope phase (CEP) of the laser pulse and the molecular orientation have a significant impact on PAD. Different molecular orientations correspond to different PADs, and a strong asymmetry is mainly caused by a larger molecular orientation in the excited state. Uni-directional photoionization can be achieved by adjusting the CEP of the laser pulse and controlling the molecular orientation in the ground state. Additionally, the duration of the laser pulse also affects the PAD.
Article
Optics
Rong-Rong Wang, Mao-Yun Ma, Jun-Ping Wang, Zhong Guan, Zhi-Hong Jiao, Wei Li, Guo-Li Wang, Jian-Hong Chen, Song-Feng Zhao
Summary: In this theoretical study, the orbital-resolved photoelectron momentum distributions (PMDs) of neon atoms in time-delayed bichromatic elliptically polarized attosecond pulses were analyzed. The interference patterns in the PMDs were found to be sensitive to various parameters of the attosecond pulses, offering possibilities for controlling interference in atoms by shaping the pulses.
EUROPEAN PHYSICAL JOURNAL D
(2022)
Article
Thermodynamics
Mohamed A. Alnakeeb, Mohamed A. Abdel Salam, Mohamed A. Hassab
Summary: Phase-change materials store large amounts of energy in small spaces, but have poor thermal conductivity. This study used numerical analysis to investigate the impact of angular orientation on the charging rate and time of a double tube latent heat storage system. The findings showed that decreasing the aspect ratio increases the average charging rate, and the inner tube with an aspect ratio of 0.5 and angular orientation of 90 degrees had the highest average charging rate.
CASE STUDIES IN THERMAL ENGINEERING
(2022)
Article
Biochemical Research Methods
Yuanli Dai, Chang Sun, Yunhe Yang, Shuanghao Wang, Huihui Li, David Da Yong Chen
Summary: The thermodynamic properties of molecular recognition in host-guest inclusion complexes were studied using Taylor dispersion analysis (TDA). TDA provided rapid and convergent results for the binding properties of cyclodextrins (CDs) and their derivatives with physiologically active substances. The TDA results were compared with those obtained by nuclear magnetic resonance and affinity capillary electrophoresis (ACE), showing slightly lower binding constants from ACE.
Article
Polymer Science
Antonietta Cozzolino, Baku Nagendra, Paola Rizzo, Christophe Daniel, Gaetano Guerra
Summary: The ability of poly(2,6-dimethyl-1,4-phenylene)oxide (PPO) films to absorb organic pollutants dissolved in water is shown. The crystalline structure and orientation on the film surface play a significant role in determining the absorption efficiency.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Chemistry, Physical
Wanda Navarra, Ida Ritacco, Olga Sacco, Lucia Caporaso, Matteo Farnesi Camellone, Vincenzo Venditto, Vincenzo Vaiano
Summary: The beneficial effects of doping and heterojunctions on the photo-catalytic activity of ZnO and TiO2 were investigated. The presence of ZnO and N-doped TiO2 in the heterojunction resulted in a decrease in band gap energy and improved photocatalytic performance compared to N-doped TiO2 and ZnO alone.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Biochemistry & Molecular Biology
Ramona Orlacchio, Simona Zuppolini, Iriczalli Cruz-Maya, Stefania Pragliola, Anna Borriello, Vincenzo Guarino, Rosalba Fittipaldi, Mariateresa Lettieri, Vincenzo Venditto
Summary: Poly-L-lactic acid (PLLA) aerogel-based scaffolds were prepared using a single step method of solvent extraction with supercritical CO2. The pore distribution and size of the aerogels were influenced by the solvent used and the crystalline forms present in the physical nodes. PLLA/CPO aerogels showed higher compressive strength, more homogeneous porosity, better biocompatibility, and cell viability than PLLA/BzOMe aerogels. Coating the aerogels with polydopamine (PDA) further improved the biocompatibility of PLLA/CPO aerogels.
Article
Chemistry, Physical
Marina Pellegrino, Adriano Fiumarella, Alma Moretta, Christophe Daniel, Marco Trifuoggi, Anna Borriello, Vincenzo Venditto
Summary: This paper describes the preparation and characterization of highly porous monolithic aerogels made from poly(2,6-dimethyl-1,4-phenylene)oxide (PPO), which have a hydrophobic nanoporous-crystalline phase and a hydrophilic sulfonated amorphous phase. The sulfonated aerogels showed a high water sorption capacity and faster kinetics for sorbing volatile organic compounds (VOCs) from water.
Article
Chemistry, Multidisciplinary
Rami Hador, Michael Shuster, Vincenzo Venditto, Moshe Kol
Summary: This study proposes a new approach to tolerate stereoerrors in the polymer by crowding them in a stereogradient copolymer. A zirconium complex of an amine tris(phenolate) ligand is used as a catalyst for the ring opening polymerization of meso-lactide at room temperature, and stereogradient copolymers are formed in the polymerization of mixtures of meso-lactide/L-lactide at 180 degrees C. These stereogradient copolymers exhibit enhanced crystallinities compared to stereorandom copolymers obtained with tin octanoate.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Applied
Antonietta Mancuso, Vincenzo Vaiano, Pasqualmorica Antico, Olga Sacco, Vincenzo Venditto
Summary: This work investigates the photocatalytic hydroxylation of benzene to phenol using a photoreactive polymer composite, N-doped TiO2 (N-TiO2) embedded into a syndiotactic polystyrene aerogel (N-TiO2/sPS). The composite exhibits enhanced phenol selectivity and yield compared to bare N-TiO2. The best results were achieved under visible light and acidic conditions, with a phenol selectivity of 98%, yield of 57%, and benzene conversion of 58%. The composite material can be recovered and reused without significant loss of photoreactivity and reduction in phenol yield.
Article
Polymer Science
Wanda Navarra, Olga Sacco, Vincenzo Venditto, Vincenzo Vaiano
Summary: In recent years, the focus of environmental pollution-related concern has shifted to aromatic substances due to their high stability and mutagenicity. Photocatalytic processes using TiO2 and sPS/P25 aerogel have been investigated for the conversion of nitroaromatic compounds into aniline. Under optimized conditions, an AN yield of over 99% was achieved, indicating the potential for scaling up the photocatalytic process for effective AN production from NB.
Article
Engineering, Chemical
Federica Tufano, Fabia Grisi, Chiara Costabile, Mina Mazzeo, Vincenzo Venditto, Antonella Caterina Boccia, Rosalba Fittipaldi, Lorella Izzo, Stefania Pragliola
Summary: The consumption and improper disposal of plastics have caused serious environmental concerns. New methods based on fluorescent tagging have been developed to facilitate the identification and sorting of different materials in plastic recycling. In this study, new fluorescent copolymers of polyethylene (PE) and polystyrene (PS) were synthesized and characterized for use as markers. These copolymers were found to have distinguishable fluorescent emissions even with a low concentration of only 1% in the PE/PS blends.
Article
Materials Science, Multidisciplinary
Baku Nagendra, Syed Salman, Hans Peter Bloch, Christophe Daniel, Paola Rizzo, Rosalba Fittipaldi, Gaetano Guerra
Summary: The study investigates the properties of sulfonated poly(phenylene oxide) (PPO) films with both hydrophilic amorphous phase and hydrophobic crystalline phase, achieved through solid-state film sulfonation. The semicrystalline-sulfonated PPO (SPPO) films exhibit superior hydrothermal and solvent stability compared to amorphous SPPO films. Moreover, the semicrystalline SPPO films demonstrate faster guest sorption kinetics due to the nanoporous-crystalline (NC) morphology.
ACS APPLIED POLYMER MATERIALS
(2023)
Proceedings Paper
Polymer Science
Antonietta Mancuso, Olga Sacco, Vincenzo Venditto, Wanda Navarra, Pasqualmorica Antico, Christophe Daniel, Vincenzo Vaiano
Summary: Experimental measurement and mathematical modeling were used to investigate the selective absorption of aromatic molecules (benzene, phenol, and toluene) from aqueous solutions by syndiotactic polystyrene (sPS) monolithic aerogels. The results showed high absorption efficiency for non-polar compounds (approximately 94% for toluene and approximately 77% for benzene) but poor absorption efficiency for the polar compound phenol (approximately 12%). NaCl did not affect the absorption efficiency of toluene and benzene, but phenol could not be removed from the aqueous phase in the presence of NaCl. These findings suggest that sPS aerogels can be used to selectively recover non-polar compounds from seawater.
MACROMOLECULAR SYMPOSIA
(2023)
Article
Chemistry, Physical
Wanda Navarra, Olga Sacco, Raffaella Rescigno, Christophe Daniel, Vincenzo Vaiano, Domenico Pisano, Bruno Brancato, Francesco Casertano, Mario Raiola, Vincenzo Venditto
Summary: In this study, a photocatalytic system utilizing a highly porous polymer containing commercial zinc sulfide and zero-valent iron catalyst (Fe/ZnS) was investigated for the degradation of PCE-contaminated groundwater. Experimental studies conducted on a pilot-scale photoreactor operating in continuous mode showed that PCE degradation in natural groundwater can reach 85-95%. A kinetic model was also developed and found to accurately describe the experimental data, allowing for potential scaling up of the photocatalytic system for PCE degradation.
CATALYSIS COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Baku Nagendra, Antonietta Cozzolino, Maria Rosaria Acocella, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: Films of nanoporous-crystalline poly(2,6-dimethyl-1,4-phenylene) oxide (PPO) can absorb apolar organic guest molecules effectively and also polar molecules from concentrated organic solutions. When obtained by spontaneous oxidation of benzyl alcohol (BAL) in aqueous solution, benzyl alcohol and benzoic acid (BA) in a 1/1 hydrogen-bonded dimer can be greatly absorbed by the NC PPO films, which is unprecedented for absorbent materials. This ability to absorb the BAL/BA dimer can be utilized in water purification.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Raffaella Rescigno, Olga Sacco, Vincenzo Venditto, Alessandra Fusco, Giovanna Donnarumma, Mariateresa Lettieri, Rosalba Fittipaldi, Vincenzo Vaiano
Summary: In this study, P-doped TiO2 photocatalysts with different molar percentages were prepared and their photocatalytic activity under visible light irradiation was tested. The doping of phosphorus significantly enhanced the photocatalytic activity, as evidenced by the decolorization of methylene blue dye. The most active photocatalyst also showed better performance than commercial TiO2 under simulated sunlight irradiation, and had a high inactivation efficiency against Escherichia coli.
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Antonietta Mancuso, Alessandro Gottuso, Francesco Parrino, Rosaria Anna Picca, Vincenzo Venditto, Olga Sacco, Vincenzo Vaiano
Summary: Cu, Fe, and V oxides supported on N-TiO2 were synthesized and their photocatalytic activities in phenol production were tested. Cu/N-TiO2 showed higher activity and yield compared to Fe/N-TiO2 and V/N-TiO2 due to its strong optical absorption and weak interaction with phenol molecules.
Article
Materials Science, Multidisciplinary
Baku Nagendra, Syed Salman, Christophe Daniel, Paola Rizzo, Gaetano Guerra
Summary: This study explores the influence of guest and processing conditions on the high surface area nanoporous-crystalline PPO films. The researchers found suitable preparation procedures that lead to high transparency and toughness, making them suitable for organic pollution remediation, molecular separations, and molecular sensing.
MATERIALS ADVANCES
(2023)