4.3 Article

Research on preparation of sheath-core bicomponent composite ion exchange fibers and absorption properties to metal ion

Journal

MACROMOLECULAR RESEARCH
Volume 16, Issue 1, Pages 21-30

Publisher

SPRINGER
DOI: 10.1007/BF03218956

Keywords

sheath-core bicomponent composite ion exchange fibers; cross-linkage; sulphonation; structure; metal ions; absorption property

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Based on the sheath-core bicomponent composite fibers with modified polystyrene (PS) and the modified polypropylene (PP), composite fibers obtained were further cross-linked and sulphonated with chlorosulphonic acid to produce strong acidic cation ion exchange fibers. The structures of the fibers obtained were characterized using Fourier transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC) etc. The optimal technology of the fibers obtained is discussed. The static absorption capacity of the sheath-core bicomponent composite cation exchange fibers for Zn2+, Cu2+ was determined. The absorption kinetics and major factors affecting the absorption capacities of Zn2+, Cu2+ were studied, and its chemical stability and regenerating properties were probed. The results suggest that cation exchange fibers with better mechanical properties and higher exchange capability were obtained. Moreover, this type of ion exchange fiber has good absorption properties and working stability to various metal ions. Hence, they have higher practicability.

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