Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 31, Issue 6, Pages 545-548Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900784
Keywords
addition polymerization; block copolymers; elastomers; polysiloxanes; thermoplastics
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Funding
- WACKER Chemie AG
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Poly(dimethylsiloxane) copolymers were synthesized directly from AA/BB monomers employing a CuAAC reaction (click chemistry) in a polyaddition approach. Using organic dialkynes and oligo(siloxane)s end-functionalized with azide moieties it was possible to obtain siloxane-based copolymers with TPE properties by click chemistry for the first time. As seen from DSC experiments, properties were strongly dependent on the incorporated organic comonomer.
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