Journal
MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 299, Issue 5, Pages 583-595Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201300265
Keywords
grafting; mechanical toughness; plasticizers; poly(lactide)s; reactive extrusion
Funding
- Region Wallonne
- European Community (FEDER)
- European Community (FSE)
- Fonds National de la Recherche-Luxembourg
- Centre de Recherche Public Henri Tudor
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To tune the toughness of PLA, a novel pathway to chemically modify PLA via reactive extrusion in the presence of reactive PEG derivatives is proposed. PEG methyl ether methacrylate (MAPEG) and PEG methyl ether acrylate (AcrylPEG) are melt-mixed and extruded with PLA in the presence of 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane (L101) as a free-radical initiator. Molecular characterization reveals that about 20 and 65%, respectively, of the initially introduced MAPEG and AcrylPEG can be grafted onto the PLA backbone. The plasticization effect is demonstrated by a significant decrease of the glass transition temperature and storage modulus together with a significant increase of the elongation at break as compared to neat PLA.
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