4.5 Article

Degradable Polyurethane/Soy Protein Shape-Memory Polymer Blends Prepared Via Environmentally-Friendly Aqueous Dispersions

Journal

MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 297, Issue 12, Pages 1213-1224

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201200341

Keywords

blends; degradable polymer; polyurethane dispersion; shape-memory effect

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Degradable polyurethane/soybean protein (PU/SP) shape-memory polymer blends are synthesized using an environmentally-friendly aqueous dispersion technique. The effects of SP concentration on the blend miscibility, thermal properties, hydrolytic degradation, and shape-memory behavior are investigated. The shape recovery rates are found to depend on SP concentration. A porous structure can be generated using scCO(2) foaming. This degradable blend may be an interesting multifunctional candidate material for potential biomedical applications.

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