Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 214, Issue 6, Pages 673-680Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201200673
Keywords
birefringence; lamellar assembly; non-conventional bands; poly(L-lactic acid) (PLLA); thin films
Categories
Funding
- National Science Council (NSC) of Taiwan [NSC-99-2221-E-006-014-MY3]
Ask authors/readers for more resources
Unconventional concentric up-and-down bands, differing from the conventional bright- extinction or blue/orange bands in other polymers, in poly(L-lactic acid) are found via controlled thin films. Non-birefringent and birefringent concentric banded spherulites are obtained from 350400 nm and 18002000 nm film thicknesses, respectively. Non-birefringent concentric ring-banded spherulites are arranged only by flat-on lamellae; in contrast, complex combinations of flat-on, edge-on, and round-shaped lamellae in four transitional zones are present within a single band in the thicker films of birefringent, concentric, ring-banded spherulites. Interband is an optically extinction crevice that segregates two neighboring bands. Unique lamellar arrangements at specific Tc and thickness confinement are two factors for the unconventional concentric bands.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available