4.4 Article

3D Hollow Microspheres Assembled from 1D Polyaniline Nanowires through a Cooperation Reaction

Journal

MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 210, Issue 23, Pages 2046-2051

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200900317

Keywords

cooperation effect; hollow spheres; nanofibers; polyaniline; self-assembly

Funding

  1. National Natural Science Foundation of China [50533030, 20974006]
  2. Program for New Century Excellent Talents in University [NECT08-0030]
  3. 973 Program [2010CB934701]

Ask authors/readers for more resources

Novel 3D hollow spheres (diameter approximate to 525 nm, thickness, approximate to 70 nm) self-assembled from 1D PANI nanofibers (diameter approximate to 17 nm) with conductivity of 1.11 x 10(-1) S . cm(-1) are synthesized template-free by using FeCl(3) and salicylic acid as the oxidant and dopant, respectively. In this method, the reaction of aniline with FeCl(3) and SA to form conductive PANI and the reaction of SA with FeCl(3) to produce a color complex, assigned as Fe(OR)(2+), wherein OR represents the ionized phenol, coexist. The coexistence of two reactions results in a cooperative effect of the micelle, where aniline/SA acts as as a soft template of the nanofibers and the color complex as a soft-template of the spheres, to allow the self-assembly of complex micro/nanostructures via hydrogen bonding as the driving force.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available