4.0 Article

Lattice phonons of solid phases (alpha, beta, delta, epsilon) of carbon monoxide by optical studies

Journal

LOW TEMPERATURE PHYSICS
Volume 36, Issue 5, Pages 424-438

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3432267

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Funding

  1. DFG [Jo 86-11]

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The phase diagram of solid carbon monoxide was investigated in the pressure range 0-10 GPa and temperature range 30-300 K by infrared and Raman spectroscopy. The tentative phase diagram known from the literature was expanded and specified in detail. The delta-phase region is divided into two subphases-delta(rot) and delta(loc)-similar to solid nitrogen. The pressure-temperature behavior of the elementary and combined excitations was also followed up. The vibron overtone region was carefully investigated by FTIR spectroscopy as a function of temperature at different pressures; the fundamental region was investigated by Raman spectroscopy. The features of the IR-active phonon sideband to the vibron overtone were investigated in detail in the entire pressure-temperature region. The lattice-phonon spectra were studied by Raman spectroscopy as a function of pressure (at lowest temperature) and by IR spectroscopy as a function of temperature at saturated vapor pressure. (C) 2010 American Institute of Physics.

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