Gahnite, chrysoberyl and beryl co-occurrence as accessory minerals in a highly evolved peraluminous pluton: The Belvis de Monroy leucogranite (Caceres, Spain)

Gahnite (ZnAl2O4), chrysoberyl (BeAl2O4) and beryl (Be3Al2Si6O18) have been found as accessory minerals in the external, highly fractionated, leucogranitic unit within the Hercynian reversely zoned Belvis de Monroy pluton (westernmost part of the Montes de Toledo batholith, Caceres, Spain). The highly felsic (SiO2 > 72 wt.%) and peraluminous (ACNK > 1.2) character of this leucogranite, together with the high content of some incompatible elements (F, Li, B, and P), seems to be a primary consequence of fractional crystallization in a magmatic closed-system. The high Be contents and Zn/Fe-Total ratio (>0.01) are relevant factors which have favoured the precipitation of these minerals. Moreover, the Si, Al, P, B, and F activities might be high, favouring the magmatic crystallization of such exotic mineral phases together with Be-rich cordierite, F-rich micas, sillimanite and Al-rich phosphates. In fact, the interplay between the silica and alumina activities likely controls the stabilization and the preferential crystallization of gahnite + chrysoberyl or beryl + chrysoberyl assemblages in mm-sized microdomains. The P-T crystallization conditions are constrained by the muscovite and sillimanite stability fields and the minimum granite Al2O3-saturated solidus, and have been estimated at temperatures between 670 and 700 degrees C, and pressures between 1 and 2 kbar. (C) 2013 Elsevier B.V. All rights reserved.