Oxo complexes of high-valence iron in oxidation catalysis

Evidence for a High-Spin Fe(IV) Species in the Catalytic Cycle of a Bacterial Phenylalanine Hydroxylase

(2011) Aram Joel Panay et al.   BIOCHEMISTRY

EPR,1H and2H NMR, and Reactivity Studies of the Iron–Oxygen Intermediates in Bioinspired Catalyst Systems

(2011) Oleg Y. Lyakin et al.   INORGANIC CHEMISTRY

A More Reactive Trigonal-Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site

(2011) Jason England et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Reactivity of Mononuclear Iron(V)oxo Complexes

(2011) Soumen Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Does Compound I Vary Significantly between Isoforms of Cytochrome P450?

(2011) Richard Lonsdale et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substrate-Triggered Activation of a Synthetic [Fe2(μ-O)2] Diamond Core for C–H Bond Cleavage

(2011) Genqiang Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

An abiotic analogue of the diiron(iv)oxo “diamond core” of soluble methane monooxygenase generated by direct activation of O2 in aqueous Fe(ii)/EDTA solutions: thermodynamics and electronic structure

(2011) Leonardo Bernasconi et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The Fundamental Role of Exchange-Enhanced Reactivity in CH Activation by S=2 Oxo Iron(IV) Complexes

(2010) Deepa Janardanan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

(2010) Olga V. Makhlynets et al.   CHEMISTRY-A EUROPEAN JOURNAL

High-valent diiron species generated from N-bridged diiron phthalocyanine and H2O2

(2010) Pavel Afanasiev et al.   DALTON TRANSACTIONS

Cytochrome P450: The Active Oxidant and Its Spectrum

(2010) Jonathan Rittle et al.   INORGANIC CHEMISTRY

Iron Catalyzed Competitive Olefin Oxidation andipso-Hydroxylation of Benzoic Acids: Further Evidence for an FeV═O Oxidant

(2010) Parthapratim Das et al.   INORGANIC CHEMISTRY

The Crystal Structure of a High-Spin Oxoiron(IV) Complex and Characterization of Its Self-Decay Pathway

(2010) Jason England et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

OlefinCis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an FeII/FeIVCatalytic Cycle

(2010) Paul D. Oldenburg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation, Structure, and EPR Detection of a High Spin FeIV—Oxo Species Derived from Either an FeIII—Oxo or FeIII—OH Complex

(2010) David C. Lacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Million-fold activation of the [Fe2(µ-O)2] diamond core for C–H bond cleavage

(2010) Genqiang Xue et al.   Nature Chemistry

Exchange-enhanced reactivity in bond activation by metal–oxo enzymes and synthetic reagents

(2010) Sason Shaik et al.   Nature Chemistry

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

(2009) Jihae Yoon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Synthetic High-Spin Oxoiron(IV) Complex: Generation, Spectroscopic Characterization, and Reactivity

(2009) Jason England et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substrate-Triggered Formation and Remarkable Stability of the C−H Bond-Cleaving Chloroferryl Intermediate in the Aliphatic Halogenase, SyrB2

(2009) Megan L. Matthews et al.   BIOCHEMISTRY

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Quantum chemical studies of C–H activation reactions by high-valent nonheme iron centers

(2009) Shengfa Ye et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

(2009) Oleg Y. Lyakin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron oxygenases: structure, mechanism and modelling

(2009) Al'bert A Shteinman   RUSSIAN CHEMICAL REVIEWS

An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+

(2008) Kallol Ray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Contrastingcis andtrans Effects on the Reactivity of Nonheme Oxoiron(IV) Complexes

(2008) Yuming Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Asymmetric Olefincis-Dihydroxylation with 97 % Enantiomeric Excess

(2008) Ken Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bio-inspired arenecis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

(2008) Yan Feng et al.   CHEMICAL COMMUNICATIONS

Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex

(2008) Alexander B. Sorokin et al.   CHEMICAL COMMUNICATIONS

Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies

(2008) Pieter C. A. Bruijnincx et al.   CHEMICAL SOCIETY REVIEWS

A Novel Platform for Modeling Oxidative Catalysis in Non‐Heme Iron Oxygenases with Unprecedented Efficiency

(2008) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Two-State Reactivity Rationale for Counterintuitive Axial Ligand Effects on the CH Activation Reactivity of Nonheme FeIVO Oxidants

(2008) Hajime Hirao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectra and Kinetic Studies of the Compound I Derivative of Cytochrome P450 119

(2008) Xin Sheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The nature of active species in catalytic systems based on non-heme iron complexes, hydrogen peroxide, and acetic acid for selective olefin epoxidation

(2008) E. A. Duban et al.   KINETICS AND CATALYSIS

Efficient and Selective Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Catalyst

(2008) Isaac Garcia-Bosch et al.   ORGANIC LETTERS