Journal
KINETICS AND CATALYSIS
Volume 51, Issue 1, Pages 63-68Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S0023158410010118
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Solid alkaline metal hydroxides displayed high catalytic activity and full selectivity in the aerobic oxidation of benzylic alcohols in a non-polar medium. The activity of the solid bases, in decreasing order of reactivity, was KOH > NaOH a parts per thousand << LiOH. Water, which is the only by-product of the reaction, plays a crucial role in KOH deactivation by converting the crystal phase of KOH to KOH center dot H2O, as confirmed by XRD measurements.
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