4.2 Article

Structure and Properties of CaO-MgO-SiO2 Inorganic Glass Fiber with Additives (Al2O3, Y2O3)

Publisher

JOURNAL WUHAN UNIV TECHNOLOGY
DOI: 10.1007/s11595-012-0407-5

Keywords

glass fiber; crystallization; dissolution

Funding

  1. National High Technology Research and Development Program (863 Program) of China [2009AA032503]
  2. National Natural Science Foundation of China [50872098, 51004080]
  3. Key State Laboratory Bleeding Base of Refractories and Ceramics (Wuhan University of Science and Technology) [G201004]

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Structure, crystallization and dissolution properties of CaO-MgO-SiO2 inorganic glass fiber in the presence of additives (Al2O3, Y2O3) were investigated by DTA, XRD, FTIR and ICP-AES techniques. The results show that with the addition of Al2O3 and Y2O3, the glass network structure is strengthened and the precipitation of crystals is inhibited for heat-treated fibers. Compared with Y2O3 doped fibers, Al2O3 presents more significant effects on the enhancement of silica network and the inhibition of crystallization in fibers. As for dissolution properties in physiological fluids, though the weight losses, changes of pH values and leached ions concentration lower slightly with the addition of Al2O3 and Y2O3 for the intensified network structure, and fibers still present high dissolution rates.

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