4.2 Article

Synthesis of leucite from potash feldspar

Publisher

WUHAN UNIV TECHNOLOGY
DOI: 10.1007/s11595-007-4452-4

Keywords

leucite; synthesis; potash feldspar

Funding

  1. National High Technology Research and Development Program of China [2002AA302204]
  2. Science and Technology Program of Guangdong Province of China [2001A1070102]
  3. Science and Technology Program of Guangzhou City of China

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Leucite particles were synthesized from feldspar mixed with 0% to 52% potassium nitrate fired from 800 degrees C to 1 200 degrees C by solid state method. The X-ray Diffraction (XRD) patterns show that in the temperature range from 800 degrees C to 1 200 degrees C, the leucite can be removed as the single crystalline phase. Kalsilite may be crystallized with leucite at 800 degrees C, but can be eliminated after prolonged heating. The scanning electron Microscopy (SEM) images clearly display the that crystals of micrometer scale leucite, and the leucite crystals distribute evenly in the matrix. The Thermal expansion coefficient (TEC) of the samples fabricated is as high as 20.52x 10(-6) degrees C-1 measured from 20 degrees C to 500 V. The mechanism of transformation from feldspar to leucite was proposed.

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