Article
Materials Science, Multidisciplinary
Xiedong Ren, Hu Wang, Qiang Wei, Yuan Lu, Bowen Xiao, Juan Xie
Summary: The study explores the scale formation behavior of N80 steel in CO2 environments at different temperatures and immersion times. It is found that temperature and immersion time significantly influence the electrochemical behavior, as a result of different scales formed on the steel surface. The presence of CaCO3 inhibits corrosion and the formation of FeCO3, with aragonite CaCO3 providing better protection due to its compact structure.
Article
Chemistry, Analytical
Temitope Olumide Olugbade
Summary: The study found that cold rolling of mild steel leads to improved corrosion resistance, indicated by a higher corrosion potential, reduced corrosion current density, and higher impedance in the rolled samples as compared to the unrolled ones. This suggests that mechanical deformation can enhance the corrosion properties of metallic materials.
ANALYTICAL LETTERS
(2021)
Article
Materials Science, Multidisciplinary
M. Kantha Shoba, K. Malar Mohan, K. Parthiban, K. Pazhanivel, N. Ramadoss
Summary: This study focuses on improving the working life and performance of spur gears through surface coating. Different coatings, including Al2O3-40%TiO2, Cr3C2-20%NiCr, and WC-10%Co-4%Cr, were applied to a mild steel C45 base material using the detonation thermal spray method. XRD and SEM analysis were performed to confirm material phase and examine surface topography and compositions. The coated specimens were evaluated for their contact stress, bending stress, total deformation, hardness, tensile strength, and wear resistance. The results showed that all the coated materials exhibited enhanced mechanical properties compared to uncoated C45, with WC-Co-Cr coating demonstrating the highest abrasive resistance.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2023)
Article
Chemistry, Physical
Adil Ech-chebab, Khadija Dahmani, Rachid Hsissou, Outman El Khouja, Dakeshwar Kumar Verma, Elyor Berdimurodov, Saban Erdogan, Burak Tuzun, Redouane Lachhab, Aadil Ejbouh, Mouhsine Galai, Mohamed Ebn Touhami
Summary: The inhibitory performance of epoxy polymer (TGETBAU) on mild steel (M-S) in 1.0 M HCl solution was assessed using potentiodynamic polarization and electrochemical impedance spectroscopy. The effects of TGETBAU molecule on corrosion inhibition and the adsorption of epoxy polymer on M-S surface were investigated using density functional theory calculation and molecular dynamics simulation. The highest inhibitory efficiency of 93% was achieved at 303 K with 2.0 g/L of TGETBAU. The corrosion of M-S was inhibited through Langmuir adsorption mechanism. The theoretical calculations were consistent with the experimental results. Moreover, M-S was protected in 1.0 M HCl, as confirmed by scanning electron microscopy and X-ray diffraction analysis.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Thermodynamics
Aleksandra Przylucka-Bednarska, Joanna Augustyn-Nadzieja, Marcin Rywotycki
Summary: The article investigates the high-temperature corrosion of steel S235, concluding that the oxide scale formed at higher temperatures is thicker and more homogeneous compared to lower temperatures. The surface characteristics of the oxidized layers also vary, with the layer formed at 1100 degrees C showing delamination and multiple phases, while the layer formed at 1200 degrees C is compact and uniform.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Article
Engineering, Environmental
Y. Fernine, N. Arrousse, Rajesh Haldhar, Chaitany Jayprakash Raorane, E. Ech-chihbi, Seong-Cheol Kim, F. El Hajjaji, A. Alami, M. Ebn Touhami, M. Taleb
Summary: Two novel organic aromatic thiophene derivatives, TET and OXM, were found to have significant anticorrosion properties on mild steel in an acidic environment. The effectiveness of these inhibitors was influenced by temperature, immersion time, and concentration. The adsorption mechanism of these compounds was evaluated using various techniques and theoretical calculations.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Aurelia Elena Tudose, Florentina Golgovici, Alexandru Anghel, Manuela Fulger, Ioana Demetrescu
Summary: The aim of this paper is to assess the corrosion behavior of a CrNx-coated 310 H stainless steel under simulated supercritical water conditions. The study found that the CrNx coating forms a protective oxide film during autoclaving, providing better corrosion resistance.
Article
Chemistry, Physical
K. Cherrak, M. El Massaoudi, H. Outada, M. Taleb, H. Lgaz, A. Zarrouk, S. Radi, A. Dafali
Summary: New bi-Pyrazol-Carbohydrazides, M2PyAz and B2PyAz, were synthesized and evaluated for their inhibitor effect against mild steel corrosion in 1 M HCl solution. The inhibitory efficiencies of M2PyAz and B2PyAz were found to be high, with M2PyAz showing excellent corrosion inhibition character due to its molecular size and denticity of electron donor atoms. Results from various experimental and computational methods support the conclusion that both M2PyAz and B2PyAz act as effective corrosion inhibitors in the studied system.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Inorganic & Nuclear
Amin Salhi, Abdellah Elyoussfi, Issam Azghay, Abdelmalek El Aatiaoui, Hassan Amhamdi, Mohamed El Massaoudi, M'hamed Ahari, Abdelhamid Bouyanzer, Smaail Radi, Soufian El Barkany
Summary: Corrosion is a significant issue in various industries, leading to continuous research and development of corrosion inhibitors. In this study, two phenolic Schiff bases named PSB3 and PSB4 were tested for their ability to prevent corrosion in mild steel. The results demonstrated that these inhibitors were most effective in preventing corrosion damage at lower temperatures and higher inhibitor concentrations.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Dakeshwar Kumar Verma, Savas Kaya, Elhachmia Ech-chihbi, Fadoua El-Hajjaji, Mayur Mausoom Phukan, Hassien M. Alnashiri
Summary: Two coumarin derivatives were synthesized and characterized as potential corrosion inhibitors for mild steel in hydrochloric acid. Various techniques were used to prove the inhibition potential, showing high efficiency and a protective layer on the metal surface. Computational simulations were employed to understand the interactions and mechanisms involved in the corrosive environment.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Materials Science, Multidisciplinary
A. Saady, Z. Rais, F. Benhiba, R. Salim, K. Ismaily Alaoui, N. Arrousse, F. Elhajjaji, M. Taleb, K. Jarmoni, Y. Kandri Rodi, I. Warad, A. Zarrouk
Summary: The study evaluated the inhibitory performance of imidazo[4,5-b] pyridine derivatives against mild steel corrosion in 1 M HCl, achieving a high inhibition performance of 90% for SB14a and 88% for SB9a at 0.1 mM. Experimental results were supported by Density functional theory (DFT) and molecular dynamic simulation (MD).
Article
Materials Science, Multidisciplinary
Trishelle M. Copeland-Johnson, Charles K. A. Nyamekye, Lynne Ecker, Nicola Bowler, Emily A. Smith, Raul B. Rebak, Simerjeet K. Gill
Summary: In this investigation, multi-modal characterization was used to evaluate the oxidation of Stainless Steel 304 under laboratory air and 100% steam (1200 degrees C, 2 h). Air oxidation resulted in Fe(NiMn)O4, Fe3O4, Fe(3,0CrxO4, and Cr2O3. Steam oxidation produced a dual layer structure, with a porous outer layer enriched in Fe2O3 and a sub-surface matrix of Fe3O4/Fe(3,0CrxO4 with SiO2/Fe(3_ x)SixO4. Based on these findings, an oxidation mechanism was proposed. The arrangement of oxidation products in air aligned with anticipated diffusion behavior, except for Cr2O3. However, the arrangement in steam deviated due to intergranular interactions with H2O, resulting in the formation of the sub-surface matrix.
Article
Engineering, Chemical
Manal A. El Sayed, Nahla T. Elazab, Malek Gassoumi, Magdy A. M. Ibrahim
Summary: This research presents a successful method for synthesizing nanocrystalline silver coatings using electrodeposition from an environmentally friendly electrolyte. The obtained silver coatings from this cyanide-free electrolyte exhibit bright and adherent nanocrystalline structures, and show excellent antibacterial properties against both gram-positive and gram-negative bacteria.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Biotechnology & Applied Microbiology
Yantao Liu
Summary: Hollow carbon nanospheres (HCNS)/S composites were prepared and characterized for their morphology, crystal structure, and electrochemical performance. The results showed that the as-prepared samples exhibited good electrochemical properties, which could contribute to the improvement of lithium-sulfur batteries.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2022)
Article
Chemistry, Physical
Amir Hossein Jafari Mofidabadi, Ghasem Bahlakeh, Bahram Ramezanzadeh
Summary: Optimizing the formation parameters for europium oxide film on steel surface can enhance corrosion resistance and decrease corrosion current density.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Nanoscience & Nanotechnology
Luis Jose Andres, Maria Fe Menendez, David Gomez, Ana Luisa Martinez, Noel Bristow, Jeffrey Paul Kettle, Armando Menendez, Bernardino Ruiz
Article
Multidisciplinary Sciences
Francisco Jose Alvarez, Miren Revuelta, Francisco Santaolalla, Antonia Alvarez, Hector Lafuente, Olatz Arteaga, Daniel Alonso-Alconada, Ana Sanchez-del-Rey, Enrique Hilario, Agustin Martinez-Ibargueen
Article
Metallurgy & Metallurgical Engineering
Ajith James Jose, Muthukaruppan Alagar, Sam John, Runcy Wilson
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH
(2017)
Article
Chemistry, Applied
Sam John, Alfeena Salam, Anju Maria Baby, Abraham Joseph
PROGRESS IN ORGANIC COATINGS
(2019)
Article
Materials Science, Composites
T. Sajini, Sam John, Beena Mathew
COMPOSITES SCIENCE AND TECHNOLOGY
(2019)
Proceedings Paper
Materials Science, Multidisciplinary
Ajith James Jose, Francis Chacko, Runcy Wilson, Muthukaruppan Alagar
Summary: The preparation and characterization of PEI/OFH nanocomposites demonstrate that by incorporating organically modified flurohectorite nano clay into the PEI matrix, the thermal and mechanical properties of the composite materials can be significantly improved. Moreover, the water uptake of the composites decreases gradually with the increase of filler content, while their anticorrosion properties are significantly enhanced.
MATERIALS TODAY-PROCEEDINGS
(2021)
Article
Multidisciplinary Sciences
Zachariah Pulluparampil Mathew, Keerthi Rajan, Cyril Augustine, Bincy Joseph, Sam John
Proceedings Paper
Materials Science, Multidisciplinary
Ajith James Jose, Runcy Wilson, George Jacob, Muthukaruppan Alagar
MATERIALS TODAY-PROCEEDINGS
(2019)
Proceedings Paper
Materials Science, Multidisciplinary
Shaji Joseph, Ajith James Jose, Runcy Wilson, Sabu Thomas, Kuruvilla Joseph
MATERIALS TODAY-PROCEEDINGS
(2019)
Article
Audiology & Speech-Language Pathology
Viktoria Havas, Andreu Gabarros, Montserrat Juncadella, Xavi Rifa-Ros, Gerard Plans, Juan Jose Acebes, Ruth de Diego Balaguer, Antoni Rodriguez-Fornells
BRAIN AND LANGUAGE
(2015)
Article
Area Studies
Hillary Hiner, Maria Jose Azocar
LATIN AMERICAN PERSPECTIVES
(2015)
Article
Psychology, Multidisciplinary
Diana Taboada, Mercedes Navio, Rosa Jurado, Vanesa Fernandez, Carmen Bayon, Ma Jose Alvarez, Isabel Morales, Guillermo Ponce, Gabriel Rubio, Jose Carlos Mingote, Felipe Cruz, Miguel Angel Jimenez
Article
Chemistry, Applied
Heena, Komal Sharma, Kamlesh Kumar, Bhargab Das, Raj Kumar
Summary: In this study, holographic films were prepared using an automatic film applicator, and their performance was compared with films prepared by other methods. The results showed that holographic films prepared with the automatic film applicator had higher diffraction efficiency and more uniform thickness, making them suitable for holographic applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Athira S. Vijayan, Antony Joseph, Abey Joseph, T. S. Abhijith, Baiju G. Nair, V. Sajith
Summary: Novel polydopamine functionalized ceria-zirconia nanoparticles filled water-borne epoxy nanocomposite coatings were developed to prevent microbial-induced corrosion of mild steel. The coatings exhibited exceptional anti-biofouling and anti-biocorrosion properties due to the synergistic effect of PDA functionalization and zirconium incorporation, providing significant enhancement in charge transfer resistance and coating resistance.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yudan Yi, Qingyong Sun, Qijun Li, Bi Shi, Ya-nan Wang
Summary: Producing metal-free leather is an effective approach to eliminate Cr pollution and achieve sustainable development of the leather industry. However, current metal-free tanning technologies have limitations in terms of water sorption and charge properties. By using cationic amphiphilic acrylic copolymers (PSD) as retanning agents, the properties of metal-free leather can be significantly improved, including enhanced hydrophobicity, better dye absorption, and excellent filling effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yunqing Xia, Lifen Tong, Xiaofang Feng, Hubing Xiang, Yi He, Xiaobo Liu
Summary: By incorporating functionalized nanofillers, such as polydopamine-modified graphitic carbon nitride and cerium oxide, into epoxy coatings, their corrosion resistance can be improved and their protective period can be extended.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Weineng Lu, Guanhao Ma, Jinqing Qu
Summary: Four novel bis-chalcone-based carbazole derivative photoinitiators were designed and synthesized in this study. Their maximum absorption wavelengths were determined and found to exhibit high molar extinction coefficients. Furthermore, a three-component photoinitiation system including bis-chalcone/iodonium/amine was successfully used to trigger the rapid and efficient photopolymerization of acrylates. The photoinitiators also showed good photo bleaching and biocompatibility, making them suitable for applications such as 3D printing and deep coating curing.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Xingnan Zhou, Shixian Zhang, Yiheng Song, Hongmei Qin, Chuanxi Xiong, Shan Wang, Quanling Yang, Delong Xie, Rong Fan, Dan Chen
Summary: In this study, eco-friendly 3-amino-1,2,4-triazole (ATA) molecules were used to modify graphene oxide (GO) nanosheets for improving the anti-corrosion performance of water-borne epoxy (WEP) coating. The results show that ATA modification enhances the dispersion of GO in the polymer coating and significantly improves the barrier effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Hao Fu, Wei Bing, Xushibojie Liu
Summary: In this study, temperature-sensitive coatings with bacteria-killing and bacteria-releasing functions were prepared on silicone rubber surfaces by UV polymerization and UV photocatalysis. The modified surface exhibited strong and persistent bactericidal effect, inhibiting the formation of bacterial biofilm. Moreover, the smart surface can effectively release bacteria and resist bacterial adhesion through temperature changes. The modified silicone rubber surface showed good biocompatibility without cytotoxicity.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Lee Eyann, Zulkifli Mohamad Ariff, Mohamad Danial Shafiq, Raa Khimi Shuib, Muhamad Sharan Musa
Summary: By investigating the effect of MAA addition on the properties of the WEA core-shell emulsion, film and coating, it was found that MAA can significantly impact the structure and performance of the coatings, and has great potential for applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Jinkyu Choi, Kyung Hoon Min, Byeong Seok Kim, Sung-Hyeon Baeck, Sang Eun Shim, Yingjie Qian
Summary: A novel phosphorus-based flame retardant was designed by incorporating aryl groups, which effectively improved the flame retardancy and mechanical properties of polyurethanes.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Saowaluk Taechutrakul, Thananchai Piroonpan, Beata Paulina Rurarz, Slawomir Kadlubowski, Piotr Ulanski, Wanvimol Pasanphan
Summary: This study proposes the use of nanogels to disperse and stabilize water-insoluble organic pigment particles in water-based inks. The nanogels were prepared using electron beam-induced chemical reactions and showed good dispersion and stabilization properties. The use of nanogels in ink formulation improved the ink's hiding power, lightfastness, and resistance properties.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Shan Wan, Huikai Chen, Bokai Liao, Xingpeng Guo
Summary: In this study, 2-amino-5 mercapto-1,3,4-thiadiazole (ATT) was used as an intercalating agent to prepare ATT/BNNS nanofillers via a liquid-phase assisted ultrasound method. TEM results showed that ATT successfully exfoliated BNNS and reduced agglomeration. The WEP ATT/BNNS coating exhibited the best protective performance under saline immersion due to the combined action of ATT inhibitor and BNNS physical barrier.
PROGRESS IN ORGANIC COATINGS
(2024)
Review
Chemistry, Applied
Lijie Yin, Bo Zhang, Ming Tian, Nanying Ning, Wencai Wang
Summary: This paper reviews the recent progress in the synthesis of bio-based waterborne polyurethanes (BWPU) and focuses on its applications in coatings, adhesives, and antimicrobials. BWPU has attracted much attention due to its good physical and chemical properties, no VOCs emissions, exploitation of renewable substances, and structural design-ability.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yuyang Zhou, Yang Chen, Xinming Cao, Haodong Fu, Yun Li, Yonghui Zhang, Jun Ma, Xin Liu
Summary: This study proposes a strategy to fabricate a high-strength double-layer superhydrophobic actuator, which consists of a metal/glass-based superhydrophobic substrate and a polymer superhydrophobic coating. The coating has high adhesive strength, self-cleaning, anti-ultraviolet irradiation, and anti-stripping properties, along with photothermal and magnetic response capabilities, enabling its application in various fields.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Fengbiao Chen, Fei Gao, Xinru Guo, Yu Chen, Xuelang Gao, Liang Shen
Summary: In this study, various covalent adaptable networks (CANs) were synthesized using multifunctional amines and compared with CANs prepared from primary and secondary amines. The results showed that the performance of CANs is closely related to the crosslinking density, and increasing the content of secondary amines improves the performance but weakens the dynamics.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Qian Zhang, Mengyi Shen, Xingcai Liu, Hao Fu, Wenbo Yang, Jinyuan Zhao, Jian Wang, Yaping Du, Chunjie Ma
Summary: Rare earth-containing corrosion inhibitors were successfully synthesized and added into epoxy coatings for the anti-corrosion of steel materials. The results showed that the coatings with rare earth elements had better anti-corrosion performance, and this difference in performance could be explained by the inherent properties of rare earth elements.
PROGRESS IN ORGANIC COATINGS
(2024)