4.4 Article

Surface Resistivity and Mechanical Properties of Rotationally Molded Polyethylene/Graphite Composites

Journal

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
Volume 19, Issue 4, Pages 258-270

Publisher

WILEY
DOI: 10.1002/vnl.21316

Keywords

-

Funding

  1. National Research Foundation of South Africa (Institutional Research Development Programme, IRDP)
  2. Xyris Technology CC

Ask authors/readers for more resources

Antistatic polymers are required to dissipate static charges safely from component surfaces. Our overall objective has been to develop cost-effective flame-retarded and antistatic polyethylene compounds suitable for rotomolding. This communication considers the surface resistivity and mechanical properties of rotationally molded linear low-density polyethylene (LLDPE)/graphite composites containing natural Zimbabwean graphite, expandable graphite, or expanded graphite. Dry blending and melt compounding were employed to obtain antistatic composites at the lowest graphite contents. Dry blending was found to be an effective mixing method for rotomolding antistatic LLDPE/graphite composites, thereby eliminating an expensive compounding step. Dry-blended Zimbabwean graphite composites showed the lowest surface resistivity at all graphite contents, with a surface resistivity of 10(5) /square at 10 wt% loading. Although rotomolded powders obtained following the melt compounding of Zimbabwean graphite exhibited higher resistivity values, the variability was much lower. Injection molding resulted in surface resistivity values above 10(14) /square for all compositions used. The rotomolded composites exhibited poor mechanical properties, in contrast to injection-molded composites. The Halpin-Tsai model showed good fits to the tensile modulus data for injection-molded Zimbabwean and expandable graphite. (c) 2013 Society of Plastics Engineers

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Multidisciplinary

Thermal properties of polyethylene flame retarded with expandable graphite and intumescent fire retardant additives

Hermanus Joachim Kruger, Walter Wilhelm Focke, Washington Mhike, Albertus Taute, Albert Roberson

FIRE AND MATERIALS (2017)

Review Materials Science, Composites

Rotomolded antistatic and flame-retarded graphite nanocomposites

Washington Mhike, Walter W. Focke, Joseph K. O. Asante

JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS (2018)

Article Thermodynamics

Stearyl alcohol/palm triple pressed acid-graphite nanocomposites as phase change materials

Washington Mhike, Walter W. Focke, Jodi Mackenzie, Edward J. Mills, Heinrich Badenhorst

THERMOCHIMICA ACTA (2018)

Article Polymer Science

Polyethylene Flame Retarded with Expandable Graphite and a Novel Intumescent Additive

Walter Wilhelm Focke, Hermanus Joachim Kruger, Washington Mhike, Albertus Taute, Albert Roberson, Osei Ofosu

JOURNAL OF APPLIED POLYMER SCIENCE (2014)

Article Polymer Science

Flame Retarding Effect of Graphite in Rotationally Molded Polyethylene/Graphite Composites

Washington Mhike, Ignatius V. W. Ferreira, Jing Li, Stanislav I. Stoliarov, Walter W. Focke

JOURNAL OF APPLIED POLYMER SCIENCE (2015)

Article Engineering, Multidisciplinary

Cone calorimeter study of polyethylene flame retarded with expandable graphite and intumescent fire-retardant additives

Hermanus Joachim Kruger, Walter Wilhelm Focke, Washington Mhike, Albertus Taute, Albert Roberson, Osei Ofosu

JOURNAL OF FIRE SCIENCES (2014)

Article Polymer Science

Flexible PVC flame retarded with expandable graphite

Walter Wilhelm Focke, Herminio Muiambo, Washington Mhike, Hermanus Joachim Kruger, Osei Ofosu

POLYMER DEGRADATION AND STABILITY (2014)

Article Thermodynamics

Characterization of commercial expandable graphite fire retardants

Walter Wilhelm Focke, Heinrich Badenhorst, Washington Mhike, Hermanus Joachim Kruger, Dewan Lombaard

THERMOCHIMICA ACTA (2014)

Article Chemistry, Multidisciplinary

Adsorption of phenol and chromium (VI) from aqueous solution using exfoliated graphite: Equilibrium, kinetics and thermodynamic studies

Siyabulela J. Tshemese, Washington Mhike, Shepherd M. Tichapondwa

Summary: In this study, Exfoliated Graphite (EG) was investigated as an adsorbent for the removal of Cr (VI) and phenol from industrial effluents. The removal efficiency was found to be highest for Cr (VI) under acidic conditions (pH 2) and for phenol under basic conditions (pH 12). Three non-linear adsorption models were evaluated, with Redlich-Peterson and Langmuir isotherms found to describe the equilibrium data for Cr (VI) and phenol, respectively. The study also concluded that the adsorption of phenol and Cr (VI) onto EG was a feasible, endothermic and spontaneous process.

ARABIAN JOURNAL OF CHEMISTRY (2021)

No Data Available