4.7 Article

Thermal degradation of Pb(Zr0.53Ti0.47 )O3/poly(vinylidene fluoride) composites as a function of ceramic grain size and concentration

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 114, Issue 2, Pages 757-763

Publisher

SPRINGER
DOI: 10.1007/s10973-012-2918-x

Keywords

Functional composites; Polymer-matrix composites; Smart materials; Thermal properties; Thermogravimetric analysis

Funding

  1. FEDER funds through the Programa Operacional Factores de Competitividade-COMPETE''
  2. FCT-Fundacao para a Ciencia e a Tecnologia [PTDC/CTM/69316/2006, PTDC/CTM-NAN/112574/2009, NANO/NMed-SD/0156/2007]
  3. FCT [SFRH/BD/22506/2005, SFRH/BD/68499/2010, SFRH/BPD/63148/2009]
  4. COST Action, European Scientific Network for Artificial Muscles'' (ESNAM) [MP1003]
  5. Fundação para a Ciência e a Tecnologia [SFRH/BD/22506/2005] Funding Source: FCT

Ask authors/readers for more resources

Poly(vinylidene fluoride)/Pb(Zr0.53Ti0.47)O-3,([PVDF](1-x)/[PZT](x)) composites of volume fractions x and (0-3) type connectivity were prepared in the form of thin films. PZT powders with average grain sizes of 0.2, 0.84, and 2.35 mu m in different volume fraction of PZT up to 40 % were mixed with the polymeric matrix. The influence of the inorganic particle size and its content on the thermal degradation properties of the composites was then investigated by means of thermo-gravimetric analysis. It is observed that filler size affects more than filler concentration the degradation temperature and activation energy of the polymer. In the same way and due to their larger specific area, smaller particles leave larger solid residuals after the polymer degradation. The polymer degradation mechanism is not significantly modified by the presence of the inorganic fillers. On the other hand, an inhibition effect occurs due to the presence of the fillers, affecting particularly the activation energy of the process.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Review Chemistry, Physical

Next generation 2D materials for anodes in battery applications

Madhu Raj Kumar, Sangeeta Singh, Heba Mohamed Fahmy, Neeraj K. Jaiswal, Seckin Akin, Ahmed Esmail Shalan, Senentxu Lanceros-Mendez, Manuel Salado

Summary: This review provides an overview of the synthesis and application of 2D materials for lithium-ion batteries, discussing the main issues in synthesis methods, material properties, and problems and proposed solutions during charging and discharging.

JOURNAL OF POWER SOURCES (2023)

Review Materials Science, Multidisciplinary

Are lead-free relaxor ferroelectric materials the most promising candidates for energy storage capacitors?

A. R. Jayakrishnan, J. P. B. Silva, K. Kamakshi, D. Dastan, V Annapureddy, M. Pereira, K. C. Sekhar

Summary: Dielectric capacitors offer high-power density and ultrafast discharging times, making them potential candidates for pulsed power technologies. However, low energy density in different dielectric materials limits their real time applications. Relaxor ferroelectrics have emerged as the most promising solution for energy storage capacitors. This review discusses the latest developments on lead-free relaxor ferroelectrics and strategies to enhance their energy storage performance.

PROGRESS IN MATERIALS SCIENCE (2023)

Article Engineering, Mechanical

Wear behavior of a new composite formulation, with TEOS addition, for abrasive vitrified grinding wheels

P. Capela, S. Costa, M. S. Souza, S. Carvalho, M. Pereira, L. Carvalho, J. R. Gomes, D. Soares

Summary: This research improved the performance of vitrified abrasive composites by adding TEOS, enhancing tool performance, dimensional stability, porosity, wear properties, and grinding ratio. It also improved the surface roughness of workpieces.
Article Materials Science, Multidisciplinary

Humidity Sensors Based on Magnetic Ionic Liquids Blended in Poly(vinylidene fluoride-co-hexafluoropropylene)

Joao P. Serra, Liliana C. Fernandes, Nelson Pereira, Arkaitz Fidalgo-Marijuan, Jose M. Porro, Carlos M. Costa, Daniela M. Correia, Senentxu Lanceros-Mendez

Summary: PVDF-HFP films incorporating different types of imidazolium ionic liquids with different magnetic anions and imidazolium cation chain lengths have been developed for humidity-sensing applications. The IL/PVDF-HFP composites exhibit a porous structure independently of the IL anion type and cation chain length. The inclusion of ILs induces polymer crystallization into the electroactive beta phase, with the most noticeable increase observed for PVDF-HFP/[Bmim][FeCl4]. The hybrid samples show a decrease in thermal stability and yield strength, with PVDF-HFP/[Bmim]2[Co(SCN)4] samples experiencing the most significant decrease. PVDF-HFP/[Bmim]2[Co-(SCN)4] and PVDF-HFP/[Bmim][FeCl4] composites display the highest magnetization. The PVDF-HFP/[Bmim]2[CoCl4] composite exhibits the highest relative humidity sensing response. The developed IL/polymer composites show potential for humidity sensing applications.

ACS APPLIED POLYMER MATERIALS (2023)

Article Biochemistry & Molecular Biology

Development of Silk Fibroin Scaffolds for Vascular Repair

David Duran-Rey, Ricardo Brito-Pereira, Clarisse Ribeiro, Sylvie Ribeiro, Juan A. Sanchez-Margallo, Veronica Crisostomo, Igor Irastorza, Unai Silvan, Senentxu Lanceros-Mendez, Francisco M. Sanchez-Margallo

Summary: SF-based biomaterials, including films, porous membranes, and electrospun membranes, were studied for their suitability in tissue regeneration applications. Regardless of their architecture, all SF-based materials showed similar chemical composition, melting transition, hydrophobic behavior, and low cytotoxicity levels. Furthermore, all of the SF-based materials promoted the proliferation of human umbilical vein endothelial cells.

BIOMACROMOLECULES (2023)

Article Polymer Science

Wastewater Treatment of Real Effluents by Microfiltration Using Poly(vinylidene fluoride-hexafluoropropylene) Membranes

Djamila Zioui, Pedro Manuel Martins, Lamine Aoudjit, Hugo Salazar, Senentxu Lanceros-Mendez

Summary: The increasing contamination of wastewater, mainly caused by industrial processes, has led to an increase in waterborne diseases. This study focuses on the development and application of a PVDF-HFP porous membrane for the remediation of a wide range of contaminants from industrial wastewater. The membrane showed high permeability and demonstrated effective removal of organic matter, salinity, and certain inorganic anions and heavy metals. The PVDF-HFP membrane and the designed membrane reactor provide a viable and cost-effective solution for the simultaneous removal of organic and inorganic contaminants in real industrial effluents.

POLYMERS (2023)

Article Chemistry, Physical

Influence of Solvent Evaporation Temperature on the Performance of Ternary Solid Polymer Electrolytes Based on Poly(vinylidene fluoride-co-hexafluoropropylene) Combining an Ionic Liquid and a Zeolite

Joao C. Barbosa, Daniela M. Correia, Arkaitz Fidalgo-Marijuan, Renato Goncalves, Stanislav Ferdov, Veronica de Zea Bermudez, Carlos M. Costa, Senentxu Lanceros-Mendez

Summary: Solid polymer electrolytes (SPEs) based on PVDF-HFP polymer, CPT zeolite, and [Bmim][SCN] ionic liquid were prepared by solvent evaporation at different temperatures. The higher ionic conductivity and lithium transference number were achieved at room temperature and 160 degrees C. The SPE prepared at 160 degrees C showed the highest discharge capacity at C/10 and C/2 rates. The control of solvent evaporation temperature allows for optimization of solid-state battery performance.

ACS APPLIED ENERGY MATERIALS (2023)

Article Nanoscience & Nanotechnology

High Performance Ternary Solid Polymer Electrolytes Based on High Dielectric Poly(vinylidene fluoride) Copolymers for Solid State Lithium-Ion Batteries

Joao C. Barbosa, Daniela M. Correia, Arkaitz Fidalgo-Marijuan, Renato Goncalves, Stanislav Ferdov, Veronica de Zea Bermudez, Senentxu Lanceros-Mendez, Carlos M. Costa

Summary: Renewable energy sources require efficient energy storage systems, and lithium-ion batteries are a standout option. However, there is still room for improvement in terms of safety and cycling stability. By implementing solid polymer electrolytes (SPEs) instead of the commonly used separator/electrolyte system, these issues can be addressed. This study focuses on the development of ternary SPEs based on specific host polymers, fillers, and ionic liquids to enhance the performance of lithium-ion batteries in terms of conductivity, stability, and cyclability.

ACS APPLIED MATERIALS & INTERFACES (2023)

Review Chemistry, Multidisciplinary

Smart and Multifunctional Materials Based on Electroactive Poly(vinylidene fluoride): Recent Advances and Opportunities in Sensors, Actuators, Energy, Environmental, and Biomedical Applications

Carlos M. Costa, Vanessa F. Cardoso, Pedro Martins, Daniela M. Correia, Renato Goncalves, Pedro Costa, Vitor Correia, Clarisse Ribeiro, Margarida M. Fernandes, Pedro M. Martins, Senentxu Lanceros-Mendez

Summary: This article reviews the latest advances and applications of poly(vinylidene fluoride) (PVDF) and its derivatives, highlighting the characteristics of PVDF materials, especially their outstanding electroactive properties, and their application in areas such as sensors and energy harvesting.

CHEMICAL REVIEWS (2023)

Article Biochemistry & Molecular Biology

Designing antimicrobial biomembranes via clustering amino-modified cellulose nanocrystals on silk fibroin β-sheets

Estela O. Carvalhoab, Mikel Rincon-Iglesias, Ricardo Brito-Pereira, Erlantz Lizundia, Margarida M. Fernandes, Senentxu Lanceros-Mendez

Summary: The development of new bio-based materials with unique chemical and structural features is essential for addressing the global healthcare concern of rising infections caused by multidrug-resistant pathogens. In this study, an antimicrobial biomaterial was created by blending amino-modified cellulose with silk fibroin, resulting in a material with improved crystallinity and antibacterial activity. This material has the potential to be used in biomedical applications, such as coatings for medical devices to control healthcare-associated infections, without the need for external antimicrobial agents.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Chemistry, Physical

Thermoelectric study of Co2FeAl thin films grown onto flexible P(VDF TrFE-CFE) terpolymer

Armando Ferreira, Carlos M. Costa, Marcio A. Correa, Rafael S. Pinto, Renato Gonsalves, Luana C. Benetti, Senentxu Lanceros-Mendez, Filipe Vaz

Summary: The necessity for energy conversion solutions has increased in recent years, particularly for powering small and flexible IoT devices. This study explores the use of thermoelectric effects, specifically the anomalous Nernst effect, by producing Co2FeAl/P(VDF-TrFE-CFE) heterostructures on flexible poly (vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) substrates. The results demonstrate that the flexible polymer substrate does not affect the thermomagnetic effect, opening new possibilities for integrating flexible high-dielectric polymers with thermomagnetic phenomena for energy harvesting applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Retraction Chemistry, Multidisciplinary

撤稿声明: Silver-Doped Cadmium Selenide/Graphene Oxide-Filled Cellulose Acetate Nanocomposites for Photocatalytic Degradation of Malachite Green toward Wastewater Treatment (Retraction of Vol 6, Pg 23129, 2021)

Mohamed K. Ahmed, Ahmed Esmail Shalan, Mohamed Afifi, Mohamed M. El-Desoky, Senentxu Lanceros-Mendez

ACS OMEGA (2023)

Review Chemistry, Multidisciplinary

Ionic liquids in the scope of lithium-ion batteries: from current separator membranes to next generation sustainable solid polymer electrolytes

J. C. Barbosa, D. M. Correia, R. Goncalves, V. de Zea Bermudez, S. Lanceros-Mendez, C. M. Costa

Summary: This article presents a perspective on the use of ionic liquids for lithium-ion batteries, focusing on their potential applications and their role in replacing harmful battery components. The future trends in using ionic liquids for battery systems are discussed, highlighting their ability to address sustainability issues without compromising performance. Overall, the article emphasizes the importance of ionic liquids in energy storage systems.

MATERIALS CHEMISTRY FRONTIERS (2023)

Review Materials Science, Multidisciplinary

A review on 2D-ZnO nanostructure based biosensors: from materials to devices

M. Sankush Krishna, Sangeeta Singh, Maria Batool, Heba Mohamed Fahmy, Kondaiah Seku, Ahmed Esmail Shalan, Senentxu Lanceros-Mendez, Muhammad Nadeem Zafar

Summary: This review presents the recent advances and applications of 2D-ZnO nanostructure-based biosensors. ZnO demonstrates various morphologies and exhibits high sensitivity and stability in biosensing applications. Different types of biosensors based on ZnO nanostructures, including optical, piezoelectric, and electrochemical sensors, are discussed. Furthermore, the review summarizes the latest research on detecting COVID-19 using ZnO nanostructures.

MATERIALS ADVANCES (2023)

No Data Available