Journal
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
Volume 76, Issue 7, Pages 955-963Publisher
SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC100904086S
Keywords
heteropolyacids; thiols; disulfides; hydrogen peroxide; Keggin type; polyoxometalate; Dawson
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The H5PV2Mo10O40 catalyzed the oxidation of thiols to their homodisulfides using hydrogen peroxide as the oxidant under mild conditions is reported. This system provides an efficient, convenient and practical method for the syntheses of symmetrical disulfides. In this work, comparisons of Keggin and Dawson type polyoxometalates are addressed in term of relative stability, hardness and acidity.
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