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H5PV2Mo10O40 as an efficient catalyst for the oxidation of thiols to the corresponding disulfides using hydrogen peroxide as the oxidant

Journal

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
Volume 76, Issue 7, Pages 955-963

Publisher

SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC100904086S

Keywords

heteropolyacids; thiols; disulfides; hydrogen peroxide; Keggin type; polyoxometalate; Dawson

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The H5PV2Mo10O40 catalyzed the oxidation of thiols to their homodisulfides using hydrogen peroxide as the oxidant under mild conditions is reported. This system provides an efficient, convenient and practical method for the syntheses of symmetrical disulfides. In this work, comparisons of Keggin and Dawson type polyoxometalates are addressed in term of relative stability, hardness and acidity.

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