Journal
POLYMERS FOR ADVANCED TECHNOLOGIES
Volume 26, Issue 7, Pages 823-828Publisher
WILEY
DOI: 10.1002/pat.3529
Keywords
poly(ionic liquid)s; ATRP; glass transition temperature
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Funding
- NSF [CHE-1400052, DMR-0969301]
- DoE [ER-45998]
- U.S. Department of Energy's National Energy Technology Laboratory [DE-FE0004000]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1400052] Funding Source: National Science Foundation
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Well-defined poly(ionic liquid)s (PILs) were synthesized by normal and activators regenerated by electron transfer atom transfer radical polymerization (ATRP) using a new ionic liquid monomer, N-(4-vinylbenzyl)-tris[2-(2-methoxyethoxy)ethyl]ammonium bis(trifluoromethylsulfonyl)imide (VBTA(+)Tf(2)N(-)). ATRP was also used for the preparation of PIL block copolymers using di-functional PIL macroinitiators. Differential scanning calorimetry measurement showed the polyVBTA(+)Tf(2)N(-) had a rather low glass transition temperature of -43 degrees C. Copyright (c) 2015 John Wiley & Sons, Ltd.
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