4.7 Article

Characteristics of Biodegradable Poly(butylene succinate) Nanocomposites With Thermally Reduced Graphene Nanosheets

Journal

POLYMER COMPOSITES
Volume 38, Issue -, Pages E42-E48

Publisher

WILEY
DOI: 10.1002/pc.23824

Keywords

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Funding

  1. Agency for Science, Technology and Research (ASTAR)
  2. Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore
  3. Petroleum Institute, Abu Dhabi, UAE

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Poly(butylene succinate) (PBS) is a biodegradable aliphatic polyester and is semicrystalline in nature. It has a wide range of engineering applications owing to its attractive combination of good processability and mechanical properties. PBS nanocomposites with graphene nanosheets were prepared by melt compounding. We report on their structure and their thermal, electrical, and mechanical properties. The thermal stability of the nanocomposite increased by 35 degrees C compared with that of neat PBS. The crystallization and melting behavior of the PBS matrix in the presence of dispersed graphene nanosheets were studied by differential scanning calorimetry and polarised optical microscope. We also observed an interesting phenomenon in the PBS/graphene nanocomposites from our FTIR investigation. -form of PBS crystals are formed in the composite samples with 5 wt% graphene loading, which otherwise forms in pure PBS only under stress. We observed approximate to 12% modulus enhancement for 2 wt% PBS/graphene nanocomposites. The electrical conductivity increased to approximate to 10(5)-fold for 5 wt% PBS/graphene nanocomposites. (C) 2015 Society of Plastics Engineers

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