4.7 Article

A fixable supramolecular cyclic polymer based on the cucurbit[8]uril-stabilized π-π interaction

Journal

POLYMER CHEMISTRY
Volume 6, Issue 38, Pages 6880-6884

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5py01131k

Keywords

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Funding

  1. Ministry of Science and Technology of China [2011CB932503]
  2. National Natural Science Foundation of China [21474020, 91227203, 31470764, 51322306]
  3. Innovation Program of the Shanghai Municipal Education Commission

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A novel reversible unimolecular cyclization method based on the CB[8]-stabilized interaction in an aqueous environment has been investigated. The dynamic properties of the cyclic PEG chain were monitored by viscometry and DLS. Upon photo-irradiation, the cyclic PEG was covalently fixed and utilized for GPC characterization.

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