4.0 Article

B(HSO4)(3): a Novel and Efficient Solid Acid Catalyst for the Regioselective Conversion of Epoxides to Thiocyanohydrins under Solvent-Free Conditions

Journal

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
Volume 19, Issue 8, Pages 1595-1599

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532008000800020

Keywords

boron sulfonic acid; solid acid; thiocyanohydrin; solvent-free; ring opening of epoxide

Funding

  1. Shahid Chamran University Research Council

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B(HSO4)(3) was easily prepared and used as a novel and efficient solid acid catalyst for conversion of epoxides to the corresponding thiocyanohydrins under solvent-free conditions with high isolated yields. The salient features of this methodology are cheaper process, easy availability of the catalyst, versatility, and high regioselectivity of the procedure.

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