4.8 Article

Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2+2]-Photocycloaddition

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 41, Pages 13185-13189

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b08100

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Funding

  1. National Science Foundation [CHE-1465075, CHE-1811795]

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The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.

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