Article
Chemistry, Physical
Ryosuke Asato, Colin J. Martin, Takuya Nakashima, Jan Patrick Calupitan, Gwenael Rapenne, Tsuyoshi Kawai
Summary: Photochromic molecules exhibit reversible isomerization reactions, with efficient energy storage efficiency and high photochemical quantum yield for cyclization reactions, enabling effective cascade cycloreversion reactions.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Ruiji Li, Qi Fang, Minghui Chen, Mihoko Yamada, Yugo Tsuji, Yusuke Kugai, Wei Li, Tsuyoshi Kawai
Summary: This study reports the synthesis and photochemical characterization of diarylethene molecular switches based on diaryl[5]helicene. The compounds exhibit reversible photochromism and turn-off mode fluorescence photoswitching upon light irradiation. The photoinduced changes in aromaticity of the central ethene bridge facilitate the thermal bleaching rates of the switches. The research provides new insight for designing aromatic diarylethene photoswitches with reversible fluorescence switching and photoinduced changes in aromaticity.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Rikuto Maegawa, Daichi Kitagawa, Shota Hamatani, Seiya Kobatake
Summary: In this study, diarylbenzenes (DABs) were designed and synthesized for high photoreactivity and fast thermal back reactivity by utilizing intramolecular CH-N hydrogen bonding and bulky substituents at reactive carbons. The enhanced photoreactivity of these DABs led to better coloration even at lower concentrations compared to previously reported DABs. The results not only offer a molecular design strategy, but also hold promise for developing environmentally friendly materials.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Physical
Zeyu Fan, Yong-Sheng Wei, Hiroyasu Tabe, Tomotaka Nakatani, Chinmoy Das, Hiroki Yamada, Satoshi Horike
Summary: We propose a new approach to create porous glassy states in coordinationpolymer (CP) and metal-organic framework (MOF) by ball milling two dense 1D crystal structures, enabling selective gas sorption and reversible photochromism.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Kristen H. H. Burns, Timothy J. J. Quincy, Christopher G. G. Elles
Summary: This paper investigates the wavelength-dependent mechanism for sequential excitation of diarylethene molecular switches, revealing enhanced vibrational modes in different excitation spectra and providing insights into the ultrafast dynamics of higher-lying excited states following sequential two-photon excitation.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Sebastian Ulrich, Xiaopu Wang, Markus Rottmar, Rene Michel Rossi, Bradley J. Nelson, Nico Bruns, Ralph Muller, Katharina Maniura-Weber, Xiao-Hua Qin, Luciano Fernandes Boesel
Summary: This study presents the first photoresist for direct laser writing of photochromic 3D micro-objects via two-photon polymerization, enabling rapid processing of complex microstructures with excellent photoresponsiveness and reversible color-changing. The work provides a new approach for custom microfabrication of 3D photochromic objects with molecularly engineered color and responsiveness.
Article
Chemistry, Multidisciplinary
Ziyong Li, Xinyu Gao, Haining Zhang, Xiaoxie Ma, Yifang Liu, Hui Guo, Jun Yin
Summary: Three novel dithienylethenes modified by bifluoroboron beta-diketonate fragments were developed, showing fast photochromic behavior, high conversion ratio, and photo-switchable bacterial imaging ability for S. aureus.
CHINESE CHEMICAL LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Shota Hamatani, Daichi Kitagawa, Rikuto Maegawa, Seiya Kobatake
Summary: In this study, nanoparticles composed of a photochromic diarylbenzene were prepared using both ball-milling and reprecipitation methods, showing different crystalline states and reversible T-type photochromic behavior. The research provides a convenient and useful way to prepare nanoparticles with different thermal back reactivity from one molecule.
MATERIALS ADVANCES
(2022)
Article
Materials Science, Ceramics
Jiahuan Yao, Xiaocui Rao, Peng Du, Weiping Li, Xiaojian Mao, Laihui Luo
Summary: In this study, bismuth layered structure ferroelectric ceramics with excellent piezoelectric performance were successfully manufactured. The influence of additive concentration on the ceramics was investigated. It was found that the ferroelectric properties were significantly enhanced after introducing Er3+ ions. Additionally, the ceramics exhibited reversible photochromic reaction and luminescence modulation.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Sivanna Chithanna, Ding-Yah Yang
Summary: The major and minor products of the photocyclization reaction of coumarinoyl enamides have been identified. Controlled experiments reveal that the formation of the minor isomer involves a stepwise radical [2+2+2] cycloreversion/cycloaddition mechanism. Deuterium labeling studies indicate that the photocyclization of both aroyl and alkenoyl enamides includes a [1,5] hydrogen shift as a key step, with different hydrogen atoms being migrated.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Guillermo Marcos-Ayuso, Marconi N. Penas-Defrutos, Ana M. Gallego, Max Garcia-Melchor, Jesus M. Martinez-Ilarduya, Pablo Espinet
Summary: This article discusses the method and importance of synthesizing aryl-alkynyl compounds. The traditional Sonogashira catalysis method is inefficient for fluorinated aryls, but an alternative method using alkynylstannanes and hemilabile PN ligands has been reported. The revision of literature reveals the existence of unreported byproducts and other factors that explain the conflict and provide clues for designing efficient alternatives for synthesizing the desired compounds.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Biochemistry & Molecular Biology
Victor Yu. Kirsanov, Elena B. Rakhimova
Summary: This review focuses on the analysis of studies published in the past 20 years regarding the chemistry of saturated annulated nitrogen-containing polycyclic compounds. These molecules consist of four to seven cycles and contain one to eight endocyclic nitrogen atoms.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Spectroscopy
Sujun Wang, Hui Zhou, Chunlin Xiong, Lin Zhou, Jingfang Han, Xiaohan Cao, Si Chen, Ziyong Li
Summary: Two novel acceptor-acceptor (A-A) type DTE derivatives (4a and 4b) were synthesized with efficient photochromism. The molecules showed solvent-dependence and excellent photoswitching behaviors in different solvents and polymer films. The study also revealed the dominant role of strong acceptor effects in the photochromic performance.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Multidisciplinary
Colin J. Martin, Yora Goto, Ryosuke Asato, Gwenael Rapenne, Tsuyoshi Kawai
Summary: Four photochromic terarylenes with extended pi-conjugated thieno[b]thiophene units were synthesized. The position of the thieno[b]thiophene units determines the exclusion of photochromic ring-cyclization and cycloreversion behavior. A spontaneous fading reaction involving both thermal and cascade cycloreversion, depending on molecular structure, was observed. Electrochemical and computational studies were conducted to investigate the relative stability of the ground and cationic states in both isomers.
NEW JOURNAL OF CHEMISTRY
(2023)
Editorial Material
Optics
Xuanhang Wang, Bin Xu, Wenjing Tian
Summary: The photochromic spiropyran molecule demonstrates a novel function in serving as an efficient photoinitiator for two-photon photopolymerization, which facilitates the development of fast 3D printing technology.
LIGHT-SCIENCE & APPLICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Takuya Nakashima, Riku Tanibe, Hiroto Yoshida, Masahiro Ehara, Miwa Kuzuhara, Tsuyoshi Kawai
Summary: Pathway-dependent chirality control in silver nanoclusters is achieved by using enantiomeric ligand, leading to the formation of chiral silver nanoclusters with intrinsic chirality. Guest binding to the nanoclusters' shell can reverse the stability between right- and left-handed nanoclusters, resulting in unprecedented chirality inversion.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Joy Ann Panis, Marine Louis, Arnaud Brosseau, Shouhei Katao, Florencio de los Reyes, Takuya Nakashima, Remi Metivier, Clemence Allain, Tsuyoshi Kawai
Summary: In this study, we synthesized two different bichromophoric difluoroboron-beta-diketonate compounds with different connectivity using cyclohexane diamine as a chiral bridge. TD-DFT calculations and experiments revealed that the connectivity variation affects the spatial arrangement and chirality inversion of the compounds. The compound with para connectivity showed higher absorption values, and ultrasonication and heating induced the formation of highly ordered nano-helical wires, leading to increased emission values.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Physical
Yasuto Nakagawa, Boda Yu, Yoshiaki Niidome, Keita Hayashi, Aleksandar Staykov, Miku Yamada, Takuya Nakashima, Tsuyoshi Kawai, Tsuyohiko Fujigaya, Tomohiro Shiraki
Summary: This study demonstrates that covalent attachment of a diarylethene derivative to single-walled carbon nanotubes introduces carbon defects, leading to near-infrared photoluminescence. Furthermore, reversible and repetitive wavelength switching of the photoluminescence is achieved based on photoisomerization of the diarylethene moieties on the nanotubes.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Organic
HaiYing Liu, Mikiya Suzuki, Kiyomi Kakiuchi, Tsuyoshi Kawai, Tsumoru Morimoto
Summary: This study reports a series of photolabile molecules based on 1,4-naphthoquinone (NQ), which can release various functional compounds under light irradiation. The synthesis of these compounds involves a concise method to attach different functional groups such as alcohols, amines, and acids. The functional compounds are masked with a common precursor and can be efficiently released through UV light irradiation.
SYNTHESIS-STUTTGART
(2023)
Article
Chemistry, Multidisciplinary
Erin Hayashi, Naoto Akiyama, Kiyomi Kakiuchi, Tsuyoshi Kawai, Tsumoru Morimoto
Summary: We developed a rhodium(I)-catalyzed asymmetric cyclohydroformylation reaction of 1,6-enynes with formaldehyde. The reaction proceeds with high enantioselectivity, producing aldehyde products with higher-order structures. This method demonstrates wide compatibility and can be successfully applied to various enynes, providing a versatile route to access chiral aldehydes.
CHEMISTRY-AN ASIAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Colin J. Martin, Yora Goto, Ryosuke Asato, Gwenael Rapenne, Tsuyoshi Kawai
Summary: Four photochromic terarylenes with extended pi-conjugated thieno[b]thiophene units were synthesized. The position of the thieno[b]thiophene units determines the exclusion of photochromic ring-cyclization and cycloreversion behavior. A spontaneous fading reaction involving both thermal and cascade cycloreversion, depending on molecular structure, was observed. Electrochemical and computational studies were conducted to investigate the relative stability of the ground and cationic states in both isomers.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Hayato Sakai, Yudai Suzuki, Makoto Tsurui, Yuichi Kitagawa, Takuya Nakashima, Tsuyoshi Kawai, Yuta Kondo, Go Matsuba, Yasuchika Hasegawa, Taku Hasobe
Summary: Chiral 1,1'-bi-2-naphthol (BINOL)-substituted boron dipyrromethene (BODIPY) derivatives with different numbers of phenyl groups were synthesized to study their aggregation-enhanced emission and circularly polarized luminescence (CPL). The self-assembly of 0Ph-B-BODIPY resulted in fibrous nanoarchitectures, while spherical nanoparticles were formed in 1Ph-B-BODIPY and 2Ph-B-BODIPY. The nanofibers of 0Ph-B-BODIPY exhibited broad emission and CPL spectra in the red to NIR regions, with enhanced dissymmetry factors compared to the monomer and 1Ph-B-BODIPY nanoparticles.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Haru Hirai, Takuya Nakashima, Shinjiro Takano, Yukatsu Shichibu, Katsuaki Konishi, Tsuyoshi Kawai, Tatsuya Tsukuda
Summary: In this study, the effects of single-atom doping on the chiroptical properties of gold superatoms were investigated. It was found that single-atom doping can improve the chiroptical properties of gold superatoms, and this study provides a rational guide for enhancing their chiroptical activity.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Marine Louis, Yan Bing Tan, Pablo Reine, Shohei Katao, Yoshiko Nishikawa, Fumio Asanoma, Tsuyoshi Kawai
Summary: This study reports on the crystal structures of three coordination polymers: [(Lambda,Lambda,Lambda,Lambda,Lambda,Lambda)- or/(Delta,Delta,Delta,Delta,Delta,Delta)Eu-6(III)(TTP)(8)(OH2)(6)Na-4]n with both conglomerate and racemic structures, (Delta,Delta,Delta,Delta)-/(Lambda,Lambda,Lambda,Lambda) Eu-4(III)(TTP)(4)(bipy)(4)(MEK)(2)(OH2)(2) with racemic tetrahedral clusters, and an achiral crystal structure of [Eu-2(III)(BTP)(4)(OH2)(2)Na-2]n (where BTP = dianionic bis-ss-diketonate, TTP = trianionic tris-ss-diketonate, and bipy = 2,2'-bipyridine). The TTP ligand's screw coordination arrangement leads to the formation of racemic EuIII products. The conglomerate crystallization of [EuIII6(TTP)8(OH2)6Na4]n is likely caused by the presence of sodium counterions and interactions between oxygen atoms and the trifluoromethyl unit of the TTP ligand and sodium ions. All Eu-III compounds exhibit characteristic red luminescence (5D0. 7FJ, J = 0-4) in solution or in the solid crystalline state. Circularly polarized luminescence (CPL) is observed in the chiral Eu-6(III)(TTP)(8)(OH2)(6)Na-4]n species, with a |glum| value ranging from 0.15 to 0.68 at the 5D0. 7F1 emission band. Subtle changes in the [Eu-6(III)(TTP)(8)(OH2)(6)Na-4]n structure, possibly due to twinned crystals or crystals that do not correspond to a perfect spontaneous resolution, account for the variation in observed CPL values.
Article
Chemistry, Physical
Mohan Zhang, Hulin Tai, Sachiko Yanagisawa, Masaru Yamanaka, Takashi Ogura, Shun Hirota
Summary: The peroxidase activity of cytochrome c increases when Met80 dissociates from the heme iron, which is related to the initial cyt c membrane permeation step of apoptosis. This study analyzed the resonance Raman spectra of Met80-depleted horse cytochrome c (M80A cyt c) to understand the heme ligand properties of Met80-dissociated cyt c. The results showed that the frequencies of Fe-His stretching and Fe-O2 stretching modes of M80A cyt c were higher than other His-ligated heme proteins, indicating strong heme coordination and the imidazolate character of His18. Moreover, the frequencies of the oxygenated species of M80A cyt c were observed to have a positive linear relationship, suggesting that the Fe-O and O-O bonds are important for the peroxidase activity when Met80 dissociates from the heme iron.
JOURNAL OF PHYSICAL CHEMISTRY B
(2023)
Article
Chemistry, Multidisciplinary
Wataru Ishii, Yoshinori Okayasu, Yoichi Kobayashi, Rika Tanaka, Shohei Katao, Yoshiko Nishikawa, Takuya Nakashima, Tsuyoshi Kawai
Summary: The optical property of an ionic metal nanocluster (NC) is affected by the ionic interaction with counter ions. The modification of trianionic [Ag29(BDT)12(TPP)4]3- NC with silver(I) complexes led to intense photoluminescence (PL) in the near-infrared (NIR) region. The binding of silver(I) complexes to the peripheral region of Ag29 NC is confirmed by various measurements, and the change in excited-state dynamics by the binding is discussed.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Ruiji Li, Qi Fang, Minghui Chen, Mihoko Yamada, Yugo Tsuji, Yusuke Kugai, Wei Li, Tsuyoshi Kawai
Summary: This study reports the synthesis and photochemical characterization of diarylethene molecular switches based on diaryl[5]helicene. The compounds exhibit reversible photochromism and turn-off mode fluorescence photoswitching upon light irradiation. The photoinduced changes in aromaticity of the central ethene bridge facilitate the thermal bleaching rates of the switches. The research provides new insight for designing aromatic diarylethene photoswitches with reversible fluorescence switching and photoinduced changes in aromaticity.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Erika Tsutsumi, Satomi Niwa, Ryota Takeda, Natsuki Sakamoto, Kei Okatsu, Shuya Fukai, Hideo Ago, Satoshi Nagao, Hiroshi Sekiguchi, Kazuki Takeda
Summary: In this study, the authors analyzed the structure of a Zn-containing form of a Rieske protein and found that zinc ions might play a role in the insertion of [2Fe-2S] clusters. They also revealed the conformational changes of the protein before metal cluster insertion.
COMMUNICATIONS CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Yugo Tsuji, Natsuko Kanno, Chigusa Goto, Shohei Katao, Yasuo Okajima, Pablo Reine, Paulius Imbrasas, Sebastian Reineke, Katsuyuki Shizu, Takuya Nakashima, Hironori Kaji, Tsuyoshi Kawai, Marine Louis
Summary: This work presents the synthesis and characterization of a carbazole-naphthalimide donor-acceptor pair for circularly polarized thermally activated delayed fluorescence. The monomeric form shows only fluorescence, while the dimeric form exhibits TADF emission. The dimerization greatly reduces the singlet-triplet energy gap, enabling TADF emission with high photoluminescence quantum yield. In addition, the chiral target shows high performance CPL at room and low temperature, and it undergoes a transition from yellow phase to orange/red phase under mechanical stress.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Wen Guo, Tieyi Lu, Ralph Crisci, Satoshi Nagao, Tao Wei, Zhan Chen
Summary: A systematic methodology combining sum frequency generation (SFG) vibrational spectroscopy, isotope labeling, spectra calculation, and computer simulation was successfully developed to determine protein molecular structures at buried solid/liquid interfaces in situ. Using this approach, the molecular structures of protein GB1 and its mutant at the polymer/solution interface were investigated, revealing markedly different orientations and similar (but not identical) conformations due to varied molecular interfacial interactions. This systematic strategy is applicable for elucidating protein structures at buried interfaces in a wide range of applications.