Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 40, Pages 15850-15853Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja205974q
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Funding
- Fonds de la Recherche Scientifique-FNRS [FRFC 2.4508.08, IISN 4.4507.10]
- INANOMAT Program [IAP-VI (P6/17)]
- Academie Universitaire Louvain
- Fonds pour la Formation a la Recherche dans l'Industrie et dans l'Agriculture
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The first crystal structures of a dinuclear iron(II) complex with three N1,N2-1,2,4-triazole bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was probed using X-ray, calorimetric, magnetic, and Fe-57 Mossbauer analyses, is also delineated in the crystalline state by variable-temperature fluorimetry for the first time.
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