Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 26, Pages 9952-9955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja203642n
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Funding
- National Institutes of Health [R01 CA137270]
- Merck Research Laboratories
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Kibdelones are hexacyclic tetrahydroxanthones and potent anticancer agents isolated from an Australian microbe. Herein, we describe the synthesis of a chiral, nonracemic iodocydohexene carboxylate EF ring fragment of the kibdelones employing an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to afford the congener kibdelone C.
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